22134
（+）-β-雪松烯
≥95.0% (sum of enantiomers, GC)
别名:
（1S,2R,5S）-8-亚甲基-2,6,6-三甲基三环[5.3.1.01.5]十一烷
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关于此项目
经验公式（希尔记法）:
C15H24
化学文摘社编号:
分子量:
204.35
UNSPSC Code:
12352002
NACRES:
NA.22
PubChem Substance ID:
EC Number:
208-898-8
Beilstein/REAXYS Number:
2244722
MDL number:
Assay:
≥95.0% (sum of enantiomers, GC)
Form:
liquid
InChI key
DYLPEFGBWGEFBB-OSFYFWSMSA-N
InChI
1S/C15H24/c1-10-7-8-15-9-12(10)14(3,4)13(15)6-5-11(15)2/h11-13H,1,5-9H2,2-4H3/t11-,12+,13+,15+/m1/s1
SMILES string
[H][C@]1(C2=C)C(C)(C)[C@@](CC[C@H]3C)([H])[C@]3(CC2)C1
assay
≥95.0% (sum of enantiomers, GC)
form
liquid
optical activity
[α]/D 11.5 to 14.5°, c = 1 in chloroform
refractive index
n20/D 1.502
bp
263-264 °C (lit.)
density
0.932 g/mL at 20 °C (lit.)
storage temp.
2-8°C
Quality Level
General description
β雪松烯是一种三环倍半萜，可从加那利刺柏和西班牙圆柏中获得。它是雪松油的主要成分，雪松油可用作开发生物燃料的原料。
Packaging
无底玻璃瓶。内含物装在锥底内插管中。
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Gloves
Use of a highly effective intramolecular Pauson-Khand cyclisation for the formal total synthesis of (?)-α-and β-cedrene by preparation of cedrone
Crawford JJ, et al.
Tetrahedron, 62(49), 11360-11370 (2006)
Renewable high density fuels containing tricyclic sesquiterpanes and alkyl diamondoids
Harrison KW and Harvey BG
Sustainable Energy & Fuels, 1(3), 467-473 (2017)
Formal Total Synthesis of (?)-α-and β-Cedrene by Preparation of Cedrone. Construction of the Tricyclic Carbon Skeleton by the Use of a Highly Efficient Intramolecular Khand Annulation
Kerr WJ, et al.
Organic Letters, 3(19), 2945-2948 (2001)
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