224286
4-甲基吗啡-N-氧化物
97%
别名:
NMO
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关于此项目
经验公式（希尔记法）:
C5H11NO2
化学文摘社编号:
分子量:
117.15
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
EC Number:
231-391-8
Beilstein/REAXYS Number:
507437
MDL number:
产品名称
4-甲基吗啡-N-氧化物, 97%
InChI key
LFTLOKWAGJYHHR-UHFFFAOYSA-N
InChI
1S/C5H11NO2/c1-6(7)2-4-8-5-3-6/h2-5H2,1H3
SMILES string
C[N+]1([O-])CCOCC1
assay
97%
reaction suitability
reagent type: oxidant
mp
180-184 °C (lit.)
functional group
ether
storage temp.
2-8°C
Quality Level
Application
用于酮的硅氰化反应的非金属催化剂。用于离子液体中 Sharpless 不对称双羟基化反应的助氧化剂。
General description
N-甲基吗啉N氧化物是一种有机化合物，在有机合成中与 OsO4和钌酸盐一起用作共氧化剂。在最近的研究中，其已用作醛酮硅氰化反应的催化剂。绿色纤维（Lyocell）是一种再生纤维素纤维，可由N-甲基吗啉N氧化物通过环保方式制得。
signalword
Danger
hcodes
Hazard Classifications
Flam. Sol. 1 - Repr. 2
存储类别
4.1B - Flammable solid hazardous materials
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
Synlett, 6, 1077-1079 (2004)
Marzieh Shafiei et al.
Bioresource technology, 102(17), 7879-7886 (2011-06-21)
Given that N-methylmorpholine-N-oxide (NMMO) is a promising alternative for the pretreatment of lignocelluloses, a novel process for ethanol and biogas production from wood was developed. The solvent, NMMO, is concentrated by multistage evaporation, and the wood is pretreated with the
N?Methylmorpholine N?Oxide
Encyclopedia of Reagents for Organic Synthesis, Second Edition (2008)
Luís C Branco et al.
The Journal of organic chemistry, 69(13), 4381-4389 (2004-06-19)
The use of room-temperature ionic liquids (RTILs) in the Sharpless catalytic asymmetric dihydroxylation (AD) as a cosolvent or replacement of the tert-butanol was studied in detail by screening 11 different RTILs. The AD reaction is faster in 1-n-butyl-3-methylimidazolium hexafluorophosphate [C(4)mim][PF(6)]
The N-Methylmorpholine-N-Oxide (NMMO) Process of Producing Regenerated Fibers
Innovative Biofibers from Renewable Resources (2014)
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