224464
D-薄荷醇
99%
别名:
(+)-薄荷醇, (1S,2R,5S)-2-异丙基-5-甲基环己醇
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关于此项目
经验公式（希尔记法）:
C10H20O
化学文摘社编号:
分子量:
156.27
UNSPSC Code:
12352212
NACRES:
NA.22
PubChem Substance ID:
EC Number:
239-387-8
Beilstein/REAXYS Number:
1902292
MDL number:
产品名称
D-薄荷醇, 99%
InChI key
NOOLISFMXDJSKH-AEJSXWLSSA-N
InChI
1S/C10H20O/c1-7(2)9-5-4-8(3)6-10(9)11/h7-11H,4-6H2,1-3H3/t8-,9+,10-/m0/s1
SMILES string
CC(C)[C@H]1CC[C@H](C)C[C@@H]1O
vapor pressure
0.8 mmHg ( 20 °C)
assay
99%
form
solid
optical activity
[α]23/D +48°, c = 10 in ethanol
optical purity
ee: 96% (GLC)
bp
103-104 °C/9 mmHg (lit.)
mp
43-44 °C (lit.)
functional group
hydroxyl
Quality Level
Gene Information
human ... UGT1A4(54657)
Application
在三甲基甲硅烷基三氟甲磺酸盐存在下，(1S,2R,5S)-(+)-薄荷醇可以与酸酐发生酰化反应，形成相应的酰化产物。
General description
(1S,2R,5S)-(+)-薄荷醇是一种手性仲醇。通过与三氯溴甲烷和四氢呋喃反应，其醇基可作为2-四氢呋喃基醚而被保护。
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 1
flash_point_f
213.8 °F - closed cup
flash_point_c
101 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Gloves
An efficient and extremely mild method for protecting alcohols as 2-tetrahydrofuranyl ethers.
Barks JM, et al.
Tetrahedron Letters, 41(32), 6249-6252 (2000)
An extremely powerful acylation reaction of alcohols with acid anhydrides catalyzed by trimethylsilyl trifluoromethanesulfonate.
Procopiou PA, et al.
The Journal of Organic Chemistry, 63(7), 2342-2347 (1998)
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