224464
D-薄荷醇
99%
别名:
(+)-薄荷醇, (1S,2R,5S)-2-异丙基-5-甲基环己醇
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关于此项目
经验公式（希尔记法）:
C10H20O
化学文摘社编号:
分子量:
156.27
UNSPSC Code:
12352212
NACRES:
NA.22
PubChem Substance ID:
EC Number:
239-387-8
Beilstein/REAXYS Number:
1902292
MDL number:
Assay:
99%
Form:
solid
vapor pressure
0.8 mmHg ( 20 °C)
Quality Level
assay
99%
form
solid
optical activity
[α]23/D +48°, c = 10 in ethanol
optical purity
ee: 96% (GLC)
bp
103-104 °C/9 mmHg (lit.)
mp
43-44 °C (lit.)
functional group
hydroxyl
SMILES string
CC(C)[C@H]1CC[C@H](C)C[C@@H]1O
InChI
1S/C10H20O/c1-7(2)9-5-4-8(3)6-10(9)11/h7-11H,4-6H2,1-3H3/t8-,9+,10-/m0/s1
InChI key
NOOLISFMXDJSKH-AEJSXWLSSA-N
Gene Information
human ... UGT1A4(54657)
General description
(1S,2R,5S)-(+)-薄荷醇是一种手性仲醇。通过与三氯溴甲烷和四氢呋喃反应，其醇基可作为2-四氢呋喃基醚而被保护。
Application
在三甲基甲硅烷基三氟甲磺酸盐存在下，(1S,2R,5S)-(+)-薄荷醇可以与酸酐发生酰化反应，形成相应的酰化产物。
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 1
flash_point_f
213.8 °F - closed cup
flash_point_c
101 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Gloves
An extremely powerful acylation reaction of alcohols with acid anhydrides catalyzed by trimethylsilyl trifluoromethanesulfonate.
Procopiou PA, et al.
The Journal of Organic Chemistry, 63(7), 2342-2347 (1998)
An efficient and extremely mild method for protecting alcohols as 2-tetrahydrofuranyl ethers.
Barks JM, et al.
Tetrahedron Letters, 41(32), 6249-6252 (2000)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 224464-10G | 04061838779069 |
| 224464-50G | 04061838779076 |