224847
一溴化碘
98%
别名:
溴化碘
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关于此项目
线性分子式:
IBr
化学文摘社编号:
分子量:
206.81
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352101
EC Number:
232-159-9
MDL number:
Assay:
98%
Form:
solid
InChI key
CBEQRNSPHCCXSH-UHFFFAOYSA-N
InChI
1S/BrI/c1-2
SMILES string
BrI
assay
98%
form
solid
mp
42-50 °C (lit.)
density
4.416 g/mL at 25 °C (lit.)
storage temp.
2-8°C
Quality Level
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General description
单溴化碘是一种卤素间化合物，在合成聚酮结构单元时用作亲电试剂。
单溴化碘（IBr）是一种在有机合成中使用的强碘化试剂。Ibr通常用于碳金属键的断裂、烯烃的亲电加成、甾体酮和醛的–金属键的断裂、烯烃的亲电加成、甾体酮和醛的 α-溴化，以及高烯丙基碳酸酯的非对映选择性环化。
单溴化碘（IBr）是一种在有机合成中使用的强碘化试剂。Ibr通常用于碳金属键的断裂、烯烃的亲电加成、甾体酮和醛的–金属键的断裂、烯烃的亲电加成、甾体酮和醛的 α-溴化，以及高烯丙基碳酸酯的非对映选择性环化。
Application
一种合成聚酮结构单元的新方法中所用的亲电试剂。
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
危险化学品
此项目有
Kai Liu et al.
Organic letters, 8(23), 5393-5395 (2006-11-03)
[Structure: see text] A strategically novel approach to the formation of syn-1,3-diol mono- and diethers through electrophilic activation of homoallylic alkoxymethyl ethers has been developed. The resulting polyketide-like synthetic fragments are generated in good yield and with excellent stereocontrol. A
The Thermodynamic Constants of Iodine Monobromide
McMorris, et al.
Journal of the American Chemical Society, 53, 2625-2631 (1931)
Iodine Monobromide
Brisbois RG, et al.
Encyclopedia of Reagents for Organic Synthesis, Second Edition, 1-5 (2001)
Serguei Patchkovskii
Physical chemistry chemical physics : PCCP, 8(8), 926-940 (2006-02-17)
Potential energy surfaces for all Born-Oppenheimer electronic states of IBr molecule correlating to the neutral (2)P ((2)P(3/2) and (2)P(1/2)) iodine and bromine are calculated for the first time. Electric dipole and polarizability curves (static and transition) are also determined. Calculations
G O Shavianidze et al.
Voprosy kurortologii, fizioterapii, i lechebnoi fizicheskoi kultury, (5)(5), 11-14 (2006-12-06)
Muscular contrapulsation (MCP) alone was used in osteoarthrosis patients as well as in combination with balneotherapy (radon and iodine-bromine baths). MCP of the lower limbs produced an analgetic and anti-inflammatory effect, improved the locomotor function, muscular tonicity, hemodynamics. MCP combination
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