质量水平
方案
98%
表单
solid
mp
42-50 °C (lit.)
密度
4.416 g/mL at 25 °C (lit.)
储存温度
2-8°C
SMILES字符串
BrI
InChI
1S/BrI/c1-2
InChI key
CBEQRNSPHCCXSH-UHFFFAOYSA-N
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一般描述
单溴化碘是一种卤素间化合物，在合成聚酮结构单元时用作亲电试剂。
单溴化碘（IBr）是一种在有机合成中使用的强碘化试剂。Ibr通常用于碳金属键的断裂、烯烃的亲电加成、甾体酮和醛的–金属键的断裂、烯烃的亲电加成、甾体酮和醛的 α-溴化，以及高烯丙基碳酸酯的非对映选择性环化。
单溴化碘（IBr）是一种在有机合成中使用的强碘化试剂。Ibr通常用于碳金属键的断裂、烯烃的亲电加成、甾体酮和醛的–金属键的断裂、烯烃的亲电加成、甾体酮和醛的 α-溴化，以及高烯丙基碳酸酯的非对映选择性环化。
应用
一种合成聚酮结构单元的新方法中所用的亲电试剂。
警示用语：
Danger
危险声明
危险分类
Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
靶器官
Respiratory system
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
危险化学品
此项目有
Iodine Monobromide
Brisbois RG, et al.
Encyclopedia of Reagents for Organic Synthesis, Second Edition, 1-5 (2001)
Kai Liu et al.
Organic letters, 8(23), 5393-5395 (2006-11-03)
[Structure: see text] A strategically novel approach to the formation of syn-1,3-diol mono- and diethers through electrophilic activation of homoallylic alkoxymethyl ethers has been developed. The resulting polyketide-like synthetic fragments are generated in good yield and with excellent stereocontrol. A
The Thermodynamic Constants of Iodine Monobromide
McMorris, et al.
Journal of the American Chemical Society, 53, 2625-2631 (1931)
A N Razumov et al.
Voprosy kurortologii, fizioterapii, i lechebnoi fizicheskoi kultury, (4)(4), 22-25 (2000-09-29)
155 patients with fragments of the crushed stones in the upper urinary tract after lithotripsy were divided into 3 groups. 60 patients of group 1 received dynamic amplipulse therapy, oral mineral water, iodobromine baths. Elimination of the fragments was observed
M Carla Aragoni et al.
Dalton transactions (Cambridge, England : 2003), (13)(13), 2252-2258 (2005-06-18)
The NBO charge distribution calculated at DFT level on the [LEX](+) species [LE=N,N'-dimethylbenzoimidazole-2(3H)-thione (3) and -2(3H)-selone (4)(Scheme 1); X=I, Br] suggests that the most likely products from the reaction 3 of 4 and with IBr are the 10-X-2 charge-transfer (CT)
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