产品名称
一溴化碘, 98%
InChI key
CBEQRNSPHCCXSH-UHFFFAOYSA-N
InChI
1S/BrI/c1-2
SMILES string
BrI
assay
98%
form
solid
mp
42-50 °C (lit.)
density
4.416 g/mL at 25 °C (lit.)
storage temp.
2-8°C
Quality Level
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Application
一种合成聚酮结构单元的新方法中所用的亲电试剂。
General description
单溴化碘是一种卤素间化合物,在合成聚酮结构单元时用作亲电试剂。
单溴化碘(IBr)是一种在有机合成中使用的强碘化试剂。Ibr通常用于碳金属键的断裂、烯烃的亲电加成、甾体酮和醛的–金属键的断裂、烯烃的亲电加成、甾体酮和醛的 α-溴化,以及高烯丙基碳酸酯的非对映选择性环化。
单溴化碘(IBr)是一种在有机合成中使用的强碘化试剂。Ibr通常用于碳金属键的断裂、烯烃的亲电加成、甾体酮和醛的–金属键的断裂、烯烃的亲电加成、甾体酮和醛的 α-溴化,以及高烯丙基碳酸酯的非对映选择性环化。
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
危险化学品
此项目有
Iodine Monobromide
Brisbois RG, et al.
Encyclopedia of Reagents for Organic Synthesis, Second Edition, 1-5 (2001)
The Thermodynamic Constants of Iodine Monobromide
McMorris, et al.
Journal of the American Chemical Society, 53, 2625-2631 (1931)
Kai Liu et al.
Organic letters, 8(23), 5393-5395 (2006-11-03)
[Structure: see text] A strategically novel approach to the formation of syn-1,3-diol mono- and diethers through electrophilic activation of homoallylic alkoxymethyl ethers has been developed. The resulting polyketide-like synthetic fragments are generated in good yield and with excellent stereocontrol. A
M Carla Aragoni et al.
Dalton transactions (Cambridge, England : 2003), (13)(13), 2252-2258 (2005-06-18)
The NBO charge distribution calculated at DFT level on the [LEX](+) species [LE=N,N'-dimethylbenzoimidazole-2(3H)-thione (3) and -2(3H)-selone (4)(Scheme 1); X=I, Br] suggests that the most likely products from the reaction 3 of 4 and with IBr are the 10-X-2 charge-transfer (CT)
Giancarlo Ottaviano et al.
American journal of otolaryngology, 32(3), 235-239 (2010-06-12)
Nasal irrigations are mentioned among the adjunctive measures for treating several sinonasal conditions. Hyperchromatic supranuclear stria (HSS) in the ciliated cells (CCs) has recently been suggested as a potential cytological marker of the anatomofunctional integrity of nasal mucosa. The aim
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