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Merck
CN

224847

一溴化碘

98%

别名:

溴化碘

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关于此项目

线性分子式:
IBr
化学文摘社编号:
分子量:
206.81
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352101
EC Number:
232-159-9
MDL number:
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产品名称

一溴化碘, 98%

InChI key

CBEQRNSPHCCXSH-UHFFFAOYSA-N

InChI

1S/BrI/c1-2

SMILES string

BrI

assay

98%

form

solid

mp

42-50 °C (lit.)

density

4.416 g/mL at 25 °C (lit.)

storage temp.

2-8°C

Quality Level

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Application

一种合成聚酮结构单元的新方法中所用的亲电试剂。

General description

单溴化碘是一种卤素间化合物,在合成聚酮结构单元时用作亲电试剂。

单溴化碘(IBr)是一种在有机合成中使用的强碘化试剂。Ibr通常用于碳金属键的断裂、烯烃的亲电加成、甾体酮和醛的–金属键的断裂、烯烃的亲电加成、甾体酮和醛的 α-溴化,以及高烯丙基碳酸酯的非对映选择性环化。

pictograms

CorrosionExclamation mark

signalword

Danger

hcodes

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

target_organs

Respiratory system

存储类别

8A - Combustible corrosive hazardous materials

wgk

WGK 3

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

法规信息

危险化学品
此项目有

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Iodine Monobromide
Brisbois RG, et al.
Encyclopedia of Reagents for Organic Synthesis, Second Edition, 1-5 (2001)
The Thermodynamic Constants of Iodine Monobromide
McMorris, et al.
Journal of the American Chemical Society, 53, 2625-2631 (1931)
Kai Liu et al.
Organic letters, 8(23), 5393-5395 (2006-11-03)
[Structure: see text] A strategically novel approach to the formation of syn-1,3-diol mono- and diethers through electrophilic activation of homoallylic alkoxymethyl ethers has been developed. The resulting polyketide-like synthetic fragments are generated in good yield and with excellent stereocontrol. A
M Carla Aragoni et al.
Dalton transactions (Cambridge, England : 2003), (13)(13), 2252-2258 (2005-06-18)
The NBO charge distribution calculated at DFT level on the [LEX](+) species [LE=N,N'-dimethylbenzoimidazole-2(3H)-thione (3) and -2(3H)-selone (4)(Scheme 1); X=I, Br] suggests that the most likely products from the reaction 3 of 4 and with IBr are the 10-X-2 charge-transfer (CT)
Giancarlo Ottaviano et al.
American journal of otolaryngology, 32(3), 235-239 (2010-06-12)
Nasal irrigations are mentioned among the adjunctive measures for treating several sinonasal conditions. Hyperchromatic supranuclear stria (HSS) in the ciliated cells (CCs) has recently been suggested as a potential cytological marker of the anatomofunctional integrity of nasal mucosa. The aim

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