224944
4-(三氟甲基)苯甲醛
98%
别名:
α,α,α-三氟对甲苯甲醛
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关于此项目
线性分子式:
CF3C6H4CHO
化学文摘社编号:
分子量:
174.12
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
207-240-7
Beilstein/REAXYS Number:
1101680
MDL number:
Assay:
98%
Form:
liquid
Quality Level
assay
98%
form
liquid
refractive index
n20/D 1.463 (lit.)
bp
66-67 °C/13 mmHg (lit.)
density
1.275 g/mL at 25 °C (lit.)
functional group
aldehyde, fluoro
SMILES string
[H]C(=O)c1ccc(cc1)C(F)(F)F
InChI
1S/C8H5F3O/c9-8(10,11)7-3-1-6(5-12)2-4-7/h1-5H
InChI key
BEOBZEOPTQQELP-UHFFFAOYSA-N
Application
- 光谱法和密度泛函理论研究得到的(Z)-1-氨基硫脲的相关数据：使用4-(三氟甲基)苯甲醛在乙醇中合成(Z)-1-[4-(三氟甲基)亚苄基]氨基硫脲（UM Osman et al., 2019）。
- 醛衍生物与三氟甲基亚磺酸钠的无过渡金属三氟甲基化反应：研究苯甲醛的直接C-H三氟甲基化和其他合成等价物（Z Tan et al., 2017）。
Other Notes
静置后可能形成沉淀，但不影响使用。轻轻加热可使固体重新溶解。
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
149.0 °F - closed cup
flash_point_c
65 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Tetrahedron, 49, 9613-9613 (1993)
Synthesis and properties of new pyridine-bridged poly (ether-imide) s based on 4-(4-trifluoromethylphenyl)-2, 6-bis [4-(4-aminophenoxy) phenyl] pyridine.
Journal of Fluorine Chemistry, 129(1), 56-63 (2008)
Peng Cao et al.
The Journal of organic chemistry, 72(17), 6628-6630 (2007-07-28)
In the presence of sodium hydrosulfite and a catalytic amount of AsPh3 and Fe(TCP)Cl, aldehydes react with ethyl diazoacetate to give the corresponding alpha,beta-unsaturated esters in high yields with excellent stereoselectivities (E/Z > 50/1).
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 224944-50G | 04061838779359 |
| 224944-10G | 04061838779342 |