225762
儿茶酚硼烷 溶液
1.0 M in THF
别名:
Catecholatoborane, Catecholborane (CB), Pyrocatecholborane
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关于此项目
经验公式（希尔记法）:
C6H5BO2
化学文摘社编号:
分子量:
119.91
NACRES:
NA.22
UNSPSC Code:
12352103
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
972072
产品名称
儿茶酚硼烷 溶液, 1.0 M in THF
InChI
1S/C6H5BO2/c1-2-4-6-5(3-1)8-7-9-6/h1-4,7H
SMILES string
[bH]1oc2ccccc2o1
InChI key
CENMEJUYOOMFFZ-UHFFFAOYSA-N
form
liquid
reaction suitability
reagent type: reductant
concentration
1.0 M in THF
density
0.958 g/mL at 25 °C
storage temp.
2-8°C
Quality Level
Application
在钛催化的芳香酮还原为醇的过程中，儿茶酚胺溶液可用作还原剂。它也可以用作二烯/三烯化合物硼氢化反应的试剂。
Legal Information
Made under U.S. Pat.No. 6,204,405.
signalword
Danger
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
target_organs
Central nervous system, Respiratory system
supp_hazards
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
1.4 °F - closed cup
flash_point_c
-17 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Asymmetric Reduction of Ketones with Catecholborane Using 2, 6-BODOL Complexes of Titanium (IV) as Catalysts
Sarvary I, et al.
Chemistry?A European Journal , 7, 2158-2166 (2001)
Synthetic Communications, 24, 1019-1019 (1994)
New synthetic strategy targeting well-defined alpha, omega-telechelic polymethylenes with hetero bi-/tri-functionalities via polyhomologation of ylides initiated by new organic boranes based on catecholborane and post functionalization
Xu F, et al.
Royal Society of Chemistry Advances, 6, 69828-69835 (2016)
Journal of the Chemical Society. Chemical Communications, 1673-1673 (1993)
Chemical Reviews, 91, 1179-1179 (1991)
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