225959
乙醚溴化镁
99%
别名:
Dibromo(1,1′-oxybis(ethane))magnesium, Dibromo(diethyl ether)magnesium, Magnesium bromide diethyl etherate, Magnesium bromide etherate
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关于此项目
线性分子式:
MgBr2 · O(C2H5)2
化学文摘社编号:
分子量:
258.23
UNSPSC Code:
12352302
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
4937320
Assay:
99%
InChI
1S/C4H10O.2BrH.Mg/c1-3-5-4-2;;;/h3-4H2,1-2H3;2*1H;/q;;;+2/p-2
SMILES string
Br[Mg]Br.CCOCC
InChI key
JGZKUKYUQJUUNE-UHFFFAOYSA-L
assay
99%
Quality Level
reaction suitability
core: magnesium
functional group
ether
Application
乙醚溴化镁作为试剂用于：
- 路易斯酸催化的狄尔斯-阿尔得反应中。
- 通过坎尼扎罗反应将芳香醛转化为醇和羧酸。
signalword
Danger
hcodes
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 3
ppe
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
Hazard Classifications
Flam. Sol. 1 - Water-react. 2
Room-temperature Cannizzaro reaction under mild conditions facilitated by magnesium bromide ethyl etherate and triethylamine
Abaee M, et al.
Organic Letters, 7, 5893-5895 (2005)
Tetrahedron Asymmetry, 2, 1193-1193 (1991)
Synthesis and Diels-Alder reactions of homochiral 2-sulfinylmaleates with cyclopentadiene
Alonso I, et al.
Tetrahedron Asymmetry, 2, 1193-1207 (1991)
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