227846
4-硝基丁酸甲酯
97%
别名:
4-Nitrobutyric acid methyl ester
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关于此项目
线性分子式:
O2N(CH2)3CO2CH3
化学文摘社编号:
分子量:
147.13
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
235-866-0
Beilstein/REAXYS Number:
1766154
MDL number:
产品名称
4-硝基丁酸甲酯, 97%
InChI key
UBSPKGKFFQKZJB-UHFFFAOYSA-N
InChI
1S/C5H9NO4/c1-10-5(7)3-2-4-6(8)9/h2-4H2,1H3
SMILES string
COC(=O)CCC[N+]([O-])=O
assay
97%
form
liquid
refractive index
n20/D 1.438 (lit.)
bp
106-110 °C/9 mmHg (lit.)
density
1.149 g/mL at 25 °C (lit.)
functional group
amine
ester
nitro
Quality Level
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Other Notes
残留物为 4-硝基戊酸甲酯
General description
The reaction of methyl 4-nitrobutyrate with aldehydes, following the enantioselective Henry addition, was studied.
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
185.0 °F - closed cup
flash_point_c
85 °C - closed cup
ppe
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
Gonzalo Blay et al.
Organic letters, 12(13), 3058-3061 (2010-06-12)
A catalytic highly enantioselective Henry addition of methyl 4-nitrobutyrate to aldehydes using a Cu(II)-amino pyridine complex as catalyst is described. The products resulting from this reaction constitute a new, highly versatile family of chiral building blocks as a result of
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