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Merck
CN

228052

二氯甲基膦

98%, solid

别名:

Dichloromethylphosphine oxide, Methanephosphonyl chloride, Methylphosphonodichloridic acid, Methylphosphonyl chloride, Methylphosphonyl dichloride

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关于此项目

线性分子式:
CH3P(O)Cl2
化学文摘社编号:
676-97-1
分子量:
132.91
NACRES:
NA.22
PubChem Substance ID:
24853672
UNSPSC Code:
12352101
EC Number:
211-634-4
MDL number:
MFCD00002071
Beilstein/REAXYS Number:
1071305

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产品名称

二氯甲基膦, 98%

InChI key

SCLFRABIDYGTAZ-UHFFFAOYSA-N

InChI

1S/CH3Cl2OP/c1-5(2,3)4/h1H3

SMILES string

CP(Cl)(Cl)=O

vapor pressure

760 mmHg ( 163 °C)

assay

98%

form

solid

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling

bp

163 °C (lit.)

mp

35-37 °C

density

1.468 g/mL at 25 °C (lit.)

Quality Level

100

Application

与氨基苯和醇发生缩合反应。

pictograms

Skull and crossbonesCorrosion
GHS06,GHS05

signalword

Danger

hcodes

H314,H330

Hazard Classifications

Acute Tox. 2 Inhalation - Eye Dam. 1 - Skin Corr. 1B

supp_hazards

EUH014

存储类别

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

230.0 °F - closed cup

flash_point_c

110 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

法规信息

监管及禁止进口产品
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCS2482
MKCR6681
MKCK5628
MKCH8639
MKCF6496

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J Rahil et al.
Biochemistry, 32(40), 10763-10772 (1993-10-12)
Four phosphonamidates were synthesized as potential beta-lactamase inhibitors. Three were methanephosphonamidates [CH3PO2-NHR/Ar, where R/Ar = 4-methoxybenzyl (3a), phenyl (3b), and m-nitrophenyl (3c)], while the fourth, PhCH2OCONHCH2PO2-NHPh (2a), also contained a beta-lactamase active site-directed amido side chain. The pH-rate profiles for
Yasuo Seto et al.
Journal of chromatography. A, 1501, 99-106 (2017-04-25)
A target analysis method for the sensitive and discriminative determination of the nerve agent hydrolysis products alkyl methylphosphonic acids as their tert-butyldimethylsilyl (TBDMS) derivatives was developed using a combination of selectable one- and two-dimensional (
Helvetica Chimica Acta, 75, 2520-2520 (1992)
Synthetic Communications, 23, 2273-2273 (1993)
Tomohide Kondo et al.
Forensic science international, 291, 23-38 (2018-08-21)
The Raman spectra of twenty-two chemical warfare agents (CWAs) were measured: eleven nerve agents and their precursor, five blister agents, three lachrymators, one choking agent, and one vomit agent, in liquid or solid state in colorless transparent vials were analyzed

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