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Merck
CN

229547

Sigma-Aldrich

硝酸铈(IV)铵

≥99.99% trace metals basis

别名:

硝酸铈铵

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关于此项目

线性分子式:
Ce(NH4)2(NO3)6
化学文摘社编号:
分子量:
548.22
EC 号:
MDL编号:
UNSPSC代码:
12352302
PubChem化学物质编号:
NACRES:
NA.23
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质量水平

方案

≥99.99% trace metals basis

表单

crystalline

反应适用性

reagent type: oxidant

杂质

≤100.0 ppm Trace Metal Analysis

SMILES字符串

N.N.[Ce+4].O[N+]([O-])=O.O[N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/Ce.2HNO3.4NO3.2H3N/c;6*2-1(3)4;;/h;2*(H,2,3,4);;;;;2*1H3/q+4;;;4*-1;;

InChI key

WIBGOERAEYJBOT-UHFFFAOYSA-N

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应用

提供通过温和条件下氧化丙二酸盐得到丙醇二酸衍生物的一种新途径。
采用硝酸铈铵引发聚丙烯酸接枝聚合,磁性阳离子交换吸附剂与胶束双水相体系偶联分离蛋白质。

警示用语:

Danger

危险分类

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Ox. Sol. 2 - Skin Corr. 1B - Skin Sens. 1A

储存分类代码

5.1B - Oxidizing hazardous materials

WGK

WGK 3

个人防护装备

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

法规信息

危险化学品
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分析证书(COA)

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Protein separation with magnetic adsorbents in micellar aqueous two-phase systems.
Becker JS, et al.
Separation and Purification Technology, 65.1, 46-53 (2009)
Nair, V. et al.
Tetrahedron Letters, 39, 2801-2801 (1998)
Alexander M Jacobine et al.
The Journal of organic chemistry, 73(18), 7409-7412 (2008-08-13)
The generation of substituted gamma-lactones can be accomplished through application of a tandem chain extension-aldol reaction, followed by CAN-mediated oxidative cleavage of the aldol product. The oxidative cleavage requires the intermediacy of a hemiketal and the presence of an alpha-heteroatom.
Ahmad Shaabani et al.
Chemical & pharmaceutical bulletin, 56(1), 79-81 (2008-01-08)
The direct conversion of alpha-hydroxy ketones and alpha-keto oximes into quinoxaline derivatives in the presence of a catalytic amount of ceric ammonium nitrate via metal-catalyzed aerobic oxidation followed by in situ trapping with aromatic 1,2-diamines in water as a green
Douglas B Grotjahn et al.
Journal of the American Chemical Society, 133(47), 19024-19027 (2011-11-09)
Organometallic iridium complexes have been reported as water oxidation catalysts (WOCs) in the presence of ceric ammonium nitrate (CAN). One challenge for all WOCs regardless of the metal used is stability. Here we provide evidence for extensive modification of many

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