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Merck
CN

229946

Sigma-Aldrich

四硼酸钠

99.998% trace metals basis

别名:

Borax,熔融

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关于此项目

线性分子式:
Na2B4O7
CAS Number:
分子量:
201.22
EC 号:
MDL编号:
UNSPSC代码:
12352302
PubChem化学物质编号:
NACRES:
NA.22
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质量水平

方案

99.998% trace metals basis

表单

powder

mp

741 °C (lit.)

密度

2.367 g/mL at 25 °C (lit.)

SMILES字符串

[Na+].[Na+].[O-]B1Ob2ob([O-])ob(O1)o2

InChI

1S/B4O7.2Na/c5-1-7-3-9-2(6)10-4(8-1)11-3;;/q-2;2*+1

InChI key

UQGFMSUEHSUPRD-UHFFFAOYSA-N

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应用

四硼酸钠也称为硼砂(Na2B4O7),可用作以下反应的催化剂:
  • 以H2O2为氧化剂将将烷基和芳基硫化物化学选择性氧化为亚砜和砜。
  • 通过Knoevenagel缩合和Michael 加成途径合成吡啶、二烯、苯胺和二氢吡喃并[3,2-c]色烯。
  • 1,2-环氧化物硫解生成β-羟基硫化物。

法律信息

象形图

Health hazardExclamation mark

警示用语:

Danger

危险声明

危险分类

Eye Irrit. 2 - Repr. 1B

储存分类代码

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 1

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Borax-Catalyzed and pH-Controlled Selective Oxidation of Organic Sulfides by H2O2: An Environmentally Clean Protocol
Hussain S, et al.
European Journal of Organic Chemistry, 2009(20), 3319-3322 (2009)
Borax-catalyzed thiolysis of 1, 2-epoxides in aqueous medium
Gao P, et al.
Tetrahedron Letters, 49(46), 6536-6538 (2008)
Shuai Liu et al.
Journal of the American Heart Association, 9(8), e014757-e014757 (2020-04-21)
Background The protective effects of polyamines on cardiovascular disease have been demonstrated in many studies. However, the roles of spermidine, a natural polyamine, in abdominal aortic aneurysm (AAA) disease have not been studied. In this study, we investigated the influence
William R Gunther et al.
Nature communications, 3, 1109-1109 (2012-10-11)
Carbohydrate epimerization is an essential technology for the widespread production of rare sugars. In contrast to other enzymes, most epimerases are only active on sugars substituted with phosphate or nucleotide groups, thus drastically restricting their use. Here we show that
Dušan Koval et al.
Analytical biochemistry, 413(1), 8-15 (2011-02-09)
Two capillary electrophoretic methods were developed and evaluated for measurement of glycated hemoglobin A1c (HbA1c). First, a capillary electrophoresis analysis is performed with a sodium tetraborate buffer (pH 9.3) as background electrolyte in a neutrally coated capillary. HbA1c is separated

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