229946
四硼酸钠
99.998% trace metals basis
别名:
Borax，熔融
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关于此项目
线性分子式:
Na2B4O7
化学文摘社编号:
分子量:
201.22
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
215-540-4
MDL number:
Assay:
99.998% trace metals basis
Form:
powder
产品名称
四硼酸钠, 99.998% trace metals basis
InChI key
UQGFMSUEHSUPRD-UHFFFAOYSA-N
InChI
1S/B4O7.2Na/c5-1-7-3-9-2(6)10-4(8-1)11-3;;/q-2;2*+1
SMILES string
[Na+].[Na+].[O-]B1Ob2ob([O-])ob(O1)o2
assay
99.998% trace metals basis
form
powder
mp
741 °C (lit.)
density
2.367 g/mL at 25 °C (lit.)
Quality Level
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Application
四硼酸钠也称为硼砂（Na2B4O7），可用作以下反应的催化剂：
- 以H2O2为氧化剂将将烷基和芳基硫化物化学选择性氧化为亚砜和砜。
- 通过Knoevenagel缩合和Michael 加成途径合成吡啶、二烯、苯胺和二氢吡喃并[3,2-c]色烯。
- 1,2-环氧化物硫解生成β-羟基硫化物。
Legal Information
signalword
Danger
hcodes
Hazard Classifications
Eye Irrit. 2 - Repr. 1B
存储类别
6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
Borax catalyzed domino reactions: synthesis of highly functionalised pyridines, dienes, anilines and dihydropyrano [3, 2-c] chromenes
Molla A and Hussain S
Royal Society of Chemistry Advances, 4(56), 29750-29758 (2014)
Borax-catalyzed thiolysis of 1, 2-epoxides in aqueous medium
Gao P, et al.
Tetrahedron Letters, 49(46), 6536-6538 (2008)
Borax-Catalyzed and pH-Controlled Selective Oxidation of Organic Sulfides by H2O2: An Environmentally Clean Protocol
Hussain S, et al.
European Journal of Organic Chemistry, 2009(20), 3319-3322 (2009)
William R Gunther et al.
Nature communications, 3, 1109-1109 (2012-10-11)
Carbohydrate epimerization is an essential technology for the widespread production of rare sugars. In contrast to other enzymes, most epimerases are only active on sugars substituted with phosphate or nucleotide groups, thus drastically restricting their use. Here we show that
Analysis of glycated hemoglobin A1c by capillary electrophoresis and capillary isoelectric focusing.
Dušan Koval et al.
Analytical biochemistry, 413(1), 8-15 (2011-02-09)
Two capillary electrophoretic methods were developed and evaluated for measurement of glycated hemoglobin A1c (HbA1c). First, a capillary electrophoresis analysis is performed with a sodium tetraborate buffer (pH 9.3) as background electrolyte in a neutrally coated capillary. HbA1c is separated
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