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Merck
CN

230022

溴化锌

99.999% trace metals basis

别名:

二溴化锌

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关于此项目

线性分子式:
ZnBr2
化学文摘社编号:
7699-45-8
分子量:
225.20
PubChem Substance ID:
24853770
eCl@ss:
38150410
UNSPSC Code:
12352302
NACRES:
NA.23
EC Number:
231-718-4
MDL number:
MFCD00011294
Assay:
99.999% trace metals basis
Form:
powder and chunks
Solubility:
diethyl ether: slightly soluble(lit.), ethanol: very soluble(lit.)

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InChI key

VNDYJBBGRKZCSX-UHFFFAOYSA-L

InChI

1S/2BrH.Zn/h2*1H;/q;;+2/p-2

SMILES string

Br[Zn]Br

assay

99.999% trace metals basis

form

powder and chunks

reaction suitability

core: zinc, reagent type: catalyst

impurities

≤15.0 ppm Trace Metal Analysis

bp

~670 °C/1 atm (lit.)

mp

394 °C (lit.)

solubility

diethyl ether: slightly soluble(lit.), ethanol: very soluble(lit.)

Quality Level

100

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相关类别

Application

二氧化硅或蒙脱石负载的溴化锌可用作 芳香族底物溴化反应的选择性催化剂。

它可作为起始原料用于制备聚氧化乙烯/锌盐系统， 该系统可用作聚合物电解质。

它也可用于制备氧化锌纳米颗粒。

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B - Skin Sens. 1

存储类别

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
0000528709
0000528709
0000528710
0000492635
0000492635

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Franz, A.K. Woerpel, K.A.
Journal of the American Chemical Society, 121, 949-949 (1999)
Yejian Han et al.
Organic letters, 13(4), 588-591 (2011-01-12)
An efficient and versatile ZnBr(2)-catalyzed Diels-Alder/carbocyclization cascade reaction has been developed for construction of highly functionalized cis-hydrindanes (70-96% yields with high diastereoselectivity), and it has been successfully utilized in the synthesis of the aglycon of dendronobiloside A.
Ruixue Deng et al.
Organic letters, 9(25), 5207-5210 (2007-11-10)
A number of indenes have been prepared in good yields by treating o-bromobenzyl zinc bromide 1 with various terminal and internal alkynes in the presence of a nickel catalyst. The nickel-catalyzed carboannulation reaction was successfully extended to the synthesis of
Erik Lundberg et al.
Journal of structural biology, 155(3), 445-457 (2006-05-26)
The transthyretin-related protein (TRP) family comprises proteins predicted to be structurally related to the homotetrameric transport protein transthyretin (TTR). The function of TRPs is not yet fully established, but recent data suggest that they are involved in purine catabolism. We
S Takeda et al.
Chemical & pharmaceutical bulletin, 48(7), 1097-1100 (2000-08-03)
The alpha,alpha-gem-difluorination of 2',4'-difluoro-alpha-(methylthio)acetophenone (1a) with N-fluoropyridinium salts gave 2',4',alpha,alpha-tetrafluoro-alpha-(methylthio)acetophenone (3a). This reaction was accelerated by the addition of zinc chloride, zinc bromide or anhydrous iron(III) chloride, and higher yields than the reaction without additives were obtained. The gem-difluorination reaction
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