230170
四丁基硼氢化铵
98%
别名:
Tetra-n-butylammonium tetrahydridoborate
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关于此项目
线性分子式:
(CH3CH2CH2CH2)4N(BH4)
化学文摘社编号:
分子量:
257.31
UNSPSC Code:
12352107
NACRES:
NA.22
PubChem Substance ID:
EC Number:
251-658-2
Beilstein/REAXYS Number:
4212332
MDL number:
Assay:
98%
Form:
solid
InChI key
GMBOFJFPOCGSOI-UHFFFAOYSA-N
InChI
1S/C16H36N.BH4/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;/h5-16H2,1-4H3;1H4/q+1;-1
SMILES string
[BH4-].CCCC[N+](CCCC)(CCCC)CCCC
assay
98%
form
solid
reaction suitability
reagent type: reductant
mp
124-128 °C (lit.)
functional group
amine
Quality Level
General description
四丁基硼氢化铵用于还原羧酸、醛和酮。
Application
β-酮酰胺、β-酮酯以及碳水化合物衍生物的选择性还原剂。
signalword
Danger
hcodes
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 3
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Hazard Classifications
Skin Corr. 1B - Water-react. 2
Tetrahedron, 49, 11169-11169 (1993)
Chemistry Letters (Jpn), 1469-1469 (1992)
Tetrabutylammonium borohydride
Raber DJ and Guida WC
eEROS (Encyclopedia of Reagents for Organic Synthesis) (2001)
Matthew N McCarroll et al.
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