230170
四丁基硼氢化铵
98%
别名:
Tetra-n-butylammonium tetrahydridoborate
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关于此项目
线性分子式:
(CH3CH2CH2CH2)4N(BH4)
化学文摘社编号:
分子量:
257.31
Beilstein:
4212332
EC 号:
MDL编号:
UNSPSC代码:
12352107
PubChem化学物质编号:
NACRES:
NA.22
方案
98%
表单
solid
反应适用性
reagent type: reductant
mp
124-128 °C (lit.)
官能团
amine
SMILES字符串
[BH4-].CCCC[N+](CCCC)(CCCC)CCCC
InChI
1S/C16H36N.BH4/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;/h5-16H2,1-4H3;1H4/q+1;-1
InChI key
GMBOFJFPOCGSOI-UHFFFAOYSA-N
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一般描述
四丁基硼氢化铵用于还原羧酸、醛和酮。
应用
β-酮酰胺、β-酮酯以及碳水化合物衍生物的选择性还原剂。
警示用语：
Danger
危险声明
危险分类
Skin Corr. 1B - Water-react 2
储存分类代码
4.3 - Hazardous materials which set free flammable gases upon contact with water
WGK
WGK 3
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Tetrahedron, 49, 11169-11169 (1993)
Chemistry Letters (Jpn), 1469-1469 (1992)
Tetrabutylammonium borohydride
Raber DJ and Guida WC
eEROS (Encyclopedia of Reagents for Organic Synthesis) (2001)
Abderrahman Atifi et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 23(53), 13076-13086 (2017-07-26)
The solvent environment around iron porphyrin complexes was examined using mixed molecular/RTIL (room temperature ionic liquid) solutions. The formation of nanodomains in these solutions provides different solvation environments for substrates that could have significant impact on their chemical reactivity. Iron
Matthew N McCarroll et al.
Nature communications, 10(1), 4078-4078 (2019-09-11)
Anesthetics are generally associated with sedation, but some anesthetics can also increase brain and motor activity-a phenomenon known as paradoxical excitation. Previous studies have identified GABAA receptors as the primary targets of most anesthetic drugs, but how these compounds produce
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