230170
四丁基硼氢化铵
98%
别名:
Tetra-n-butylammonium tetrahydridoborate
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关于此项目
线性分子式:
(CH3CH2CH2CH2)4N(BH4)
化学文摘社编号:
分子量:
257.31
UNSPSC Code:
12352107
NACRES:
NA.22
PubChem Substance ID:
EC Number:
251-658-2
Beilstein/REAXYS Number:
4212332
MDL number:
产品名称
四丁基硼氢化铵, 98%
InChI key
GMBOFJFPOCGSOI-UHFFFAOYSA-N
InChI
1S/C16H36N.BH4/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;/h5-16H2,1-4H3;1H4/q+1;-1
SMILES string
[BH4-].CCCC[N+](CCCC)(CCCC)CCCC
assay
98%
form
solid
reaction suitability
reagent type: reductant
mp
124-128 °C (lit.)
functional group
amine
Quality Level
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Application
β-酮酰胺、β-酮酯以及碳水化合物衍生物的选择性还原剂。
General description
四丁基硼氢化铵用于还原羧酸、醛和酮。
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B - Water-react 2
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 3
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Tetrabutylammonium borohydride
Raber DJ and Guida WC
eEROS (Encyclopedia of Reagents for Organic Synthesis) (2001)
Tetrahedron, 49, 11169-11169 (1993)
Chemistry Letters (Jpn), 1469-1469 (1992)
Matthew N McCarroll et al.
Nature communications, 10(1), 4078-4078 (2019-09-11)
Anesthetics are generally associated with sedation, but some anesthetics can also increase brain and motor activity-a phenomenon known as paradoxical excitation. Previous studies have identified GABAA receptors as the primary targets of most anesthetic drugs, but how these compounds produce
Abderrahman Atifi et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 23(53), 13076-13086 (2017-07-26)
The solvent environment around iron porphyrin complexes was examined using mixed molecular/RTIL (room temperature ionic liquid) solutions. The formation of nanodomains in these solutions provides different solvation environments for substrates that could have significant impact on their chemical reactivity. Iron
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