230235
二苯基次膦酰氯
98%, liquid
别名:
Ph2POCl, 二苯基次膦酰氯, 二苯基氯膦氧化物, 二苯基磷酰氯, 二苯基膦酰氯, 氯二苯基膦氧化物
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关于此项目
线性分子式:
(C6H5)2P(O)Cl
化学文摘社编号:
分子量:
236.63
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352002
EC Number:
216-107-2
MDL number:
Beilstein/REAXYS Number:
975191
产品名称
二苯基次膦酰氯, 98%
Quality Segment
assay
98%
form
liquid
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling
refractive index
n20/D 1.609 (lit.)
bp
222 °C/16 mmHg (lit.)
density
1.24 g/mL at 25 °C (lit.)
storage temp.
2-8°C
SMILES string
ClP(=O)(c1ccccc1)c2ccccc2
InChI
1S/C12H10ClOP/c13-15(14,11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10H
InChI key
QPQGTZMAQRXCJW-UHFFFAOYSA-N
Application
除了几种肽偶联剂之外，二苯基次膦酰氯（Ph2POCl）被广泛用作合成各种手性磷化氢双配位基配体（用于不对称合成）的前体。
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - Skin Sens. 1A
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
78.8 °F - closed cup
flash_point_c
26 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter