232181
1-环己烯-1-羧酸甲酯
≥97%
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关于此项目
线性分子式:
C6H9CO2CH3
化学文摘社编号:
分子量:
140.18
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
242-331-5
Beilstein/REAXYS Number:
1071971
MDL number:
产品名称
1-环己烯-1-羧酸甲酯, ≥97%
InChI
1S/C8H12O2/c1-10-8(9)7-5-3-2-4-6-7/h5H,2-4,6H2,1H3
InChI key
KXPWRCPEMHIZGU-UHFFFAOYSA-N
SMILES string
COC(=O)C1=CCCCC1
assay
≥97%
form
liquid
bp
190-192 °C
58-60 °C/0.1 mmHg (lit.)
density
1.028 g/mL at 20 °C (lit.)
functional group
ester
Quality Level
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Application
Methyl 1-cyclohexene-1-carboxylate was used in:
- diastereoselective synthesis of cis-1,2-dialkenylcyclopropanols
- synthesis of methyl 7,7-dimethyl-9-oxo-1,3,4,4a,6,7,8,9,9b-decahydrodibenzo[b,d]furan-4a-carboxylate
- synthesis of ethyl 7-oxo-7b,8,9,10,11,11a-hexahydro-7H-benzo[b]phenaleno[2,1-d]furan-11a-carboxylate
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
159.8 °F - closed cup
flash_point_c
71 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Diastereoselective Synthesis of cis-1, 2-Dialkenylcyclopropanols and Subsequent Oxy-Cope Rearrangement.
Lee J, et al.
Journal of the American Chemical Society, 117(39), 9919-9920 (1995)
Ceric ammonium nitrate (CAN)-mediated oxidative cycloaddition of 1, 3-dicarbonyls to conjugated compounds. Efficient synthesis of dihydrofurans, dihydrofurocoumarins, dihydrofuroquinolinones, dihydrofurophenalenones, and furonaphthoquinone natural products.
Lee YR, et al.
Tetrahedron, 56(45), 8845-8853 (2000)
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