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232599

甲氧基乙酸乙酯

Name: 甲氧基乙酸乙酯
Brand: ALDRICH

97%

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关于此项目

线性分子式:

CH₃OCH₂COOC₂H₅

化学文摘社编号:

3938-96-3

分子量:

118.13

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24853916

EC Number:

223-521-7

Beilstein/REAXYS Number:

1744761

MDL number:

MFCD00009176

Assay:

97%

Form:

liquid

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属性

Quality Level

200

assay

97%

form

liquid

refractive index

n20/D 1.401 (lit.)

bp

44-45.5 °C/9 mmHg (lit.)

density

1.007 g/mL at 25 °C (lit.)

functional group

ester, ether

SMILES string

CCOC(=O)COC

InChI

1S/C5H10O3/c1-3-8-5(6)4-7-2/h3-4H2,1-2H3

InChI key

JLEKJZUYWFJPMB-UHFFFAOYSA-N

说明

Application

Ethyl methoxyacetate was used:

as acyl donor during the preparation of enantiomers of several phenylethylamines
as acylation reagent for the aminolysis of 1-phenylethanamine
in an industrial, lipase-catalysed kinetic resolution of primary amine

pictograms

GHS02

signalword

Warning

hcodes

H226

Hazard Classifications

Flam. Liq. 3

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

114.8 °F - closed cup

flash_point_c

46 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

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Enzymatic enantiomeric resolution of phenylethylamines structurally related to amphetamine.

Lourdes Muñoz et al.

Organic & biomolecular chemistry, 9(23), 8171-8177 (2011-10-06)

Both enantiomers of several phenylethylamines, structurally related to amphetamine, have been prepared in good yields and excellent enantiomeric purity by enzymatic kinetic resolution using CAL-B and ethyl methoxyacetate as the acyl donor. In the case of the 4-hydroxyderivative of amphetamine

Reagents for (ir)reversible enzymatic acylations.

Ulf Hanefeld

Organic & biomolecular chemistry, 1(14), 2405-2415 (2003-09-06)

Commonly, hydrolase-catalysed reactions are used for kinetic resolutions of alcohols, amines and acids. Only a few applications in total syntheses have been described. Most of these examples are for the synthesis of amides and peptides. Here, the synthesis of all

Improved sensitivity for high resolution in situ hybridization using resin extraction of methyl methacrylate embedded material.

C Saito et al.

Biotechnic & histochemistry : official publication of the Biological Stain Commission, 74(1), 40-48 (1999-04-06)

An in situ hybridization procedure resulting in both high resolution and sensitivity was established by using the removable methyl methacrylate resin, Technovit 9100. Young bicellular pollen of tobacco (Nicotiana tabacum L. SR-1) was embedded in Technovit 9100 resin and sectioned.

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全球贸易项目编号

货号	GTIN
232599-50G	04061836683306
232599-10G	04061836675110