232750
1-溴-2-氯乙烷
98%
别名:
亚乙基氯溴化物, 氯乙基溴
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关于此项目
线性分子式:
ClCH2CH2Br
化学文摘社编号:
分子量:
143.41
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
203-456-0
Beilstein/REAXYS Number:
605265
MDL number:
Assay:
98%
Form:
liquid
InChI key
IBYHHJPAARCAIE-UHFFFAOYSA-N
InChI
1S/C2H4BrCl/c3-1-2-4/h1-2H2
SMILES string
ClCCBr
assay
98%
form
liquid
refractive index
n20/D 1.488 (lit.)
bp
106-107 °C (lit.)
mp
−18-−14 °C (lit.)
solubility
water: soluble
density
1.723 g/mL at 25 °C (lit.)
functional group
bromo, chloro
Quality Level
General description
利用直流切片成像技术对800nm飞秒激光场照射的1-溴-2-氯乙烷（BCE）的离解双电离和多光子电离进行了研究。BCE在硅铝酸盐-1、硅质Y、Na-Y和L型沸石等多种沸石中的构象特征也通过FT-拉曼光谱得到了研究。
Application
1-溴-2-氯乙烷已被用于2-亚烷基四氢呋喃的区域选择性和非对映选择性合成。
signalword
Danger
Hazard Classifications
Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Carc. 1B - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
监管及禁止进口产品
此项目有
Haiyan Wang et al.
Langmuir : the ACS journal of surfaces and colloids, 25(14), 8042-8050 (2009-04-21)
The conformational properties of 1-bromo-2-chloroethane (BCE) in several representative zeolites including silicalite-1, siliceous Y (Si-Y), Na-Y, and zeolite L have been investigated by FT-Raman spectroscopy in combination with thermogravimetric analysis. The results indicate that the conformational and dynamic behavior of
P Langer et al.
The Journal of organic chemistry, 66(18), 6057-6063 (2001-09-01)
The domino C,O-cyclodialkylation reaction of dilithiated 1,3-dicarbonyl compounds with 1,4-dibromo-2-butene resulted in regio- and diastereoselective formation of 2-alkylidene-5-vinyltetrahydrofurans. The cyclization of 1,3-dicarbonyl dianions with 1-bromo-2-chloroethane regio- and diastereoselectively afforded 2-alkylidenetetrahydrofurans under thermodynamic reaction control.
Yan Yang et al.
The Journal of chemical physics, 135(6), 064303-064303 (2011-08-17)
The dissociative double ionization and multi-photon ionization of 1-bromo-2-chloroethane (BCE) irradiated by the 800 nm femtosecond laser field have been investigated by dc-slice imaging technology. The charged parent ion ratio [BCE(2+)]/[BCE(+)] was measured, and the corresponding ionization process including non-sequential
Y Oda et al.
Carcinogenesis, 17(2), 297-302 (1996-02-01)
The Escherichia coli mu operon was subcloned into a pKK233-2 vector containing rat glutathione S-transferase (GST) 5-5 cDNA and the plasmid thus obtained was introduced into Salmonella typhimurium TA1535. The newly developed strain S.typhimurium NM5004, was found to have 52-fold
R D Storer et al.
Carcinogenesis, 4(11), 1491-1494 (1983-11-01)
Hepatic DNA damage was demonstrated by alkaline DNA unwinding/hydroxylapatite batch chromatography in male B6C3F1 mice treated with non-necrogenic doses of 1,2-dichloroethane, 1-bromo-2-chloroethane, and 1,2-dibromoethane. Intraperitoneal administration of 0.5 mmol/kg of 1-bromo-2-chloroethane and 1,2-dibromoethane produced similar levels of DNA damage. A
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