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233587

1-叔丁基-3,5-二甲基苯

Name: 1-叔丁基-3,5-二甲基苯
Brand: ALDRICH

98%

别名:

5-叔丁基-间二甲苯, 对称-叔丁基-间二甲苯

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关于此项目

线性分子式:

(CH₃)₃CC₆H₃(CH₃)₂

化学文摘社编号:

98-19-1

分子量:

162.27

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24853985

EC Number:

202-647-6

Beilstein/REAXYS Number:

1853314

MDL number:

MFCD00008832

Assay:

98%

Form:

liquid

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属性

Quality Level

100

assay

98%

form

liquid

refractive index

n20/D 1.495 (lit.)

bp

205-206 °C (lit.)

density

0.867 g/mL at 25 °C (lit.)

SMILES string

Cc1cc(C)cc(c1)C(C)(C)C

InChI

1S/C12H18/c1-9-6-10(2)8-11(7-9)12(3,4)5/h6-8H,1-5H3

InChI key

FZSPYHREEHYLCB-UHFFFAOYSA-N

说明

General description

1-叔丁基-3,5-二甲基苯参与N-苯基乙酰胺与非预官能化芳烃的级联二芳基化反应。

Application

1-叔丁基-3,5-二甲基苯已被用于合成大体积、多烷基化二芳基二硫化物，如双(4-叔丁基-2,6-二甲基苯基)二硫化物和双(2,4,6-三异丙基苯基)二硫化物。

存储类别

10 - Combustible liquids

wgk

WGK 3

flash_point_f

154.4 °F - closed cup

flash_point_c

68 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

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Metal-free direct oxidative intermolecular diarylation of anilides at ambient temperature assisted by cascade selective formation of C-C and C-N bonds.

Rajarshi Samanta et al.

Chemical communications (Cambridge, England), 48(26), 3194-3196 (2012-02-15)

A new atom-economical process of direct oxidative intermolecular functionalization of aniline derivatives by simple arenes was developed. The products were formed in a highly regioselective manner under metal-free conditions at ambient temperature.

Discovery of 4-tert-butyl-2,6-dimethylphenylsulfur trifluoride as a deoxofluorinating agent with high thermal stability as well as unusual resistance to aqueous hydrolysis, and its diverse fluorination capabilities including deoxofluoro-arylsulfinylation with high stereoselectivity.

Teruo Umemoto et al.

Journal of the American Chemical Society, 132(51), 18199-18205 (2010-12-04)

Versatile, safe, shelf-stable, and easy-to-handle fluorinating agents are strongly desired in both academic and industrial arenas, since fluorinated compounds have attracted considerable interest in many areas, such as drug discovery, due to the unique effects of fluorine atoms when incorporated

全球贸易项目编号

货号	GTIN
233587-100G	04061837704017
233587-500G	04061837704024