234273
反,反,反-1,5,9-环十二烷基三烯
99%
别名:
(1E,5E,9E)-1,5,9-Cyclododecatriene, (1E,5E,9E)-Cyclododeca-1,5,9-triene, (E,E,E)-1,5,9-Cyclododecatriene
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关于此项目
经验公式（希尔记法）:
C12H18
化学文摘社编号:
分子量:
162.27
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
211-626-0
Beilstein/REAXYS Number:
969880
MDL number:
产品名称
反,反,反-1,5,9-环十二烷基三烯, 99%
InChI key
ZOLLIQAKMYWTBR-FFWAUJBHSA-N
InChI
1S/C12H18/c1-2-4-6-8-10-12-11-9-7-5-3-1/h1-2,7-10H,3-6,11-12H2/b2-1+,9-7+,10-8+
SMILES string
C1C\C=C\CC\C=C\CC\C=C\1
assay
99%
form
solid
bp
237-238 °C (lit.)
mp
33-35 °C (lit.)
Quality Level
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Application
trans,trans,trans-1,5,9-Cyclododecatriene has been used in the construction of building block for the synthesis of potent antitumor annonaceous acetogenin (+)-parviflorin.
General description
trans,trans,trans-1,5,9-Cyclododecatriene (ttt-cdt) acts as ligand and forms rare copper complexes. Photorearrangements of CuCl complexes of ttt-cdt has been investigated.
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
163.4 °F - closed cup
flash_point_c
73 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
新产品
此项目有
Photorearrangements of CuCl complexes of 1, 5, 9-cyclododecatrienes: wavelength dependence.
Chow YL, et al.
Organometallics, 6(5), 1126-1129 (1987)
Mauro Fianchini et al.
Dalton transactions (Cambridge, England : 2003), (12)(12), 2085-2087 (2009-03-11)
Two rare copper complexes, a tri-alkene adduct [Cu(ttt-cdt)(FSbF(5))] and a non-classical carbon monoxide complex [Cu(ttt-cdt)(CO)][SbF(6)] with a high CO stretching frequency ([small nu, Greek, macron](CO) = 2160 cm(-1)), have been isolated using trans,trans,trans-1,5,9-cyclododecatriene (ttt-cdt) ligand.
Highly efficient synthesis of the potent antitumor annonaceous acetogenin (+)-parviflorin.
Hoye TR and Ye Z.
Journal of the American Chemical Society, 118(7), 1801-1802 (1996)
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