234486
3-(二甲基氨基)丙腈
98%
别名:
DMAPN
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关于此项目
线性分子式:
(CH3)2NCH2CH2CN
化学文摘社编号:
分子量:
98.15
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
217-090-4
Beilstein/REAXYS Number:
773779
MDL number:
Assay:
98%
产品名称
3-(二甲基氨基)丙腈, 98%
InChI key
MTPJEFOSTIKRSS-UHFFFAOYSA-N
InChI
1S/C5H10N2/c1-7(2)5-3-4-6/h3,5H2,1-2H3
SMILES string
CN(C)CCC#N
assay
98%
refractive index
n20/D 1.426 (lit.)
bp
171 °C/750 mmHg (lit.)
mp
−43 °C (lit.)
density
0.87 g/mL at 25 °C (lit.)
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Application
3-（二甲氨基）丙腈已被用于：
- 在I类杂化聚（N-异丙基丙烯酰胺）/二氧化硅水凝胶的合成过程中引发有机聚合
- 制备基于溶剂化变色荧光团4-N,N-二甲基氨基-1,8-萘二甲酰亚胺（4-DMN）的半胱氨酸修饰剂
类似于TEMED的催化剂用于从过硫酸铵形成氧自由基。自由基可引起丙烯酰胺和双丙烯酰胺的聚合。
General description
3-（二甲氨基）丙腈通过钯催化剂的的加氢反应已被研究。
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Eye Irrit. 2
存储类别
10 - Combustible liquids
wgk
WGK 1
flash_point_f
145.4 °F - closed cup
flash_point_c
63 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Hydrogenation of 3-(dimethylamino) propionitrile over palladium catalysts.
Krupka J, et al.
Collection of Czechoslovak Chemical Communications, 65(11), 1805-1819 (2000)
Galen Loving et al.
Bioconjugate chemistry, 20(11), 2133-2141 (2009-10-14)
The solvatochromic fluorophore 4-N,N-dimethylamino-1,8-naphthalimide (4-DMN) possesses extremely sensitive emission properties due largely to the low intrinsic fluorescence it exhibits in polar protic solvents such as water. This makes it well suited as a probe for the detection of a wide
P Banet et al.
The journal of physical chemistry. B, 113(45), 14914-14919 (2009-11-06)
Class I hybrid poly(N-isopropylacrylamide)/silica hydrogels, PNIPAM/SiO2, were prepared by a new one shot synthesis. In this approach, the free-radical polymerization of vinyl groups of N-isopropylacrylamide (NIPAM) and the hydrolysis-condensation of alkoxy groups of tetramethoxysilane (TMOS) are performed concomitantly using sodium
J R Froines et al.
Journal of toxicology and environmental health, 16(3-4), 469-479 (1985-01-01)
The neurotoxic aminonitrile dimethylaminopropionitrile (DMAPN) inhibits the crystalline glycolytic enzymes glyceraldehyde-3-phosphate dehydrogenase (GAPDH) and fructose-6-phosphate kinase (phosphofructokinase, PFK). Preincubation of GAPDH with the aminonitrile enhances the inhibition, indicating that the inhibition is irreversible. The overall bimolecular rate constant ki was
Inhibition of acetylcholinesterase by neurotoxic aminonitriles.
J R Froines
Biochemical pharmacology, 34(17), 3185-3187 (1985-09-01)
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