235083
双(三甲基硅基)氨基钠
95%
别名:
六甲基二硅氮烷 钠盐
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关于此项目
线性分子式:
[(CH3)3Si]2NNa
化学文摘社编号:
分子量:
183.37
UNSPSC Code:
12352111
NACRES:
NA.22
PubChem Substance ID:
EC Number:
213-983-8
Beilstein/REAXYS Number:
3629917
MDL number:
Assay:
95%
Form:
powder or chunks
Quality Level
assay
95%
form
powder or chunks
bp
202 °C/at 1-3 hPa
mp
171-175 °C (lit.), 175-171 °C (lit.)
SMILES string
C[Si](C)(C)N([Na])[Si](C)(C)C
InChI
1S/C6H18NSi2.Na/c1-8(2,3)7-9(4,5)6;/h1-6H3;/q-1;+1
InChI key
WRIKHQLVHPKCJU-UHFFFAOYSA-N
Application
用于卡宾的生成、亚磺酰胺的胺化以及镧系元素配合物的制备。
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
supp_hazards
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Angewandte Chemie (International Edition in English), 32, 1208-1208 (1993)
Journal of the American Chemical Society, 116, 7637-7637 (1994)
Journal of the Chemical Society. Perkin Transactions 1, 1923-1923 (1992)
Jerry Isaacson et al.
Angewandte Chemie (International ed. in English), 48(10), 1845-1848 (2009-01-29)
(-)-Dysibetaine has been synthesized in 11 steps from readily available L-malic acid (see scheme). The key step is a unique Ugi 4-center-3-component cyclization reaction, where an ester group acts as the carboxylic acid component. The use of 1,1,1,3,3,3-hexamethyldisilazane as an
Hexamethyldisilazane-mediated controlled polymerization of alpha-amino acid N-carboxyanhydrides.
Hua Lu et al.
Journal of the American Chemical Society, 129(46), 14114-14115 (2007-10-30)
商品
Discover AdQPhos and its Pd pre-catalysts for selective α-arylation of diverse nucleophiles under mild aqueous conditions without hazardous solvents.
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 235083-100G | 04061838784926 |
| 235083-5G | 04061838784940 |
| 235083-25G | 04061838784933 |
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