235105
N,O-双(三甲基硅基)羟胺
97%
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关于此项目
线性分子式:
(CH3)3SiONHSi(CH3)3
化学文摘社编号:
分子量:
177.39
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
245-188-7
Beilstein/REAXYS Number:
1920452
MDL number:
Assay:
97%
assay
97%
refractive index
n20/D 1.411 (lit.)
bp
78-80 °C/100 mmHg (lit.)
density
0.83 g/mL at 25 °C (lit.)
storage temp.
2-8°C
SMILES string
C[Si](C)(C)NO[Si](C)(C)C
InChI
1S/C6H19NOSi2/c1-9(2,3)7-8-10(4,5)6/h7H,1-6H3
InChI key
ZAEUMMRLGAMWKE-UHFFFAOYSA-N
General description
N,O-Bis(trimethylsilyl)hydroxylamine on reaction with 9-chloro-9-borafluorene yields 10-trimethylsilyloxy-9-aza-10-boraphenanthrene. It reacts with free phenolic steroids during the analysis of conjugated estrogen tablets and injectable formulations by GLC.
Application
N,O-Bis(trimethylsilyl)hydroxylamine has been used as reagent for the preparation of N-(dialkyl phosphinoyl)hydroxylamines and migration of simple alkyl groups in rearrangement of their O-p-nitrobenzenesulfonates.
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
84.2 °F - closed cup
flash_point_c
29 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Sunanda Biswas et al.
Chemical communications (Cambridge, England), 48(38), 4564-4566 (2012-04-03)
Treatment of 9-chloro-9-borafluorene with N,O-bis(trimethylsilyl)hydroxylamine results in 10-trimethylsilyloxy-9-aza-10-boraphenanthrene 6b. NMR spectroscopy shows that the expected antiaromatic 9-(trimethylsilyloxyamino)-9-borafluorene 5b rearranges to the formally aromatic phenanthrene 6b at room temperature.
Tetrahedron, 48, 7539-7539 (1992)
G K Pillai et al.
Journal of pharmaceutical sciences, 70(9), 1072-1075 (1981-09-01)
A rapid capillary GLC method for the analysis of conjugated estrogen tablets and injectable formulations is described. The method involves the hydrolytic cleavage of the sodium sulfate ester conjugates by sulfatase enzyme. The free phenolic steroids are reacted sequentially with
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 235105-1G | 04061836825904 |
| 235105-10G | 04061836818197 |