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Merck
CN

235202

4-溴甲基-7-甲氧基香豆素

97%

别名:

BMC, Br-Mmc

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关于此项目

经验公式(希尔记法):
C11H9BrO3
化学文摘社编号:
分子量:
269.09
Beilstein:
187211
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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质量水平

方案

97%

表单

solid

mp

213-215 °C (lit.)

溶解性

chloroform: soluble 20 mg/mL, clear, colorless to faintly yellow

荧光

λex 322 nm; λem 395 nm (after derivatization)

官能团

bromo
ester

SMILES字符串

COc1ccc2C(CBr)=CC(=O)Oc2c1

InChI

1S/C11H9BrO3/c1-14-8-2-3-9-7(6-12)4-11(13)15-10(9)5-8/h2-5H,6H2,1H3

InChI key

CTENSLORRMFPDH-UHFFFAOYSA-N

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应用

用于各种天然存在的酸,包括胆汁和血栓烷 B2 的衍生化反应、TLC 和 HPLC 分离以及荧光分析。
脂肪酸的荧光标记。

象形图

Exclamation mark

警示用语:

Warning

危险分类

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Brisa S Fernandes et al.
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V Hagen et al.
Journal of photochemistry and photobiology. B, Biology, 53(1-3), 91-102 (2000-02-15)
New caged derivatives of hydrolysis-resistant 8-bromoadenosine cyclic 3',5'-monophosphate (8-Br-cAMP) and 8-bromoguanosine cyclic 3',5'-monophosphate (8-Br-cGMP) are described. The compounds are the axial and equatorial isomers of the (7-methoxycoumarin-4-yl)methyl (MCM) esters of cyclic nucleotides. Synthesis is accomplished by treatment of 4-bromomethyl-7-methoxycoumarin with
Automated analysis procedure for valproic acid in blood, serum and brain dialysate by high-performance liquid chromatography with bromomethylmethoxycoumarin as fluorescent label.
J H Wolf et al.
Journal of chromatography, 487(2), 496-502 (1989-02-24)
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