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关于此项目
线性分子式:
CH3OPCl2
化学文摘社编号:
分子量:
132.91
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
221-915-3
Beilstein/REAXYS Number:
1697452
MDL number:
产品名称
二氯亚磷酸甲酯, technical grade
InChI key
HCSDJECSMANTCX-UHFFFAOYSA-N
InChI
1S/CH3Cl2OP/c1-4-5(2)3/h1H3
SMILES string
COP(Cl)Cl
grade
technical grade
form
liquid
refractive index
n20/D 1.474 (lit.)
bp
93-95 °C (lit.)
mp
−91 °C (lit.)
density
1.376 g/mL at 20 °C (lit.)
Quality Level
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Application
用于分别从亚磺酰氯和手性氨基醇合成硫代二氯磷酸酯以及氮氧杂膦烷。
signalword
Danger
hcodes
Hazard Classifications
Flam. Liq. 3 - Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
supp_hazards
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
77.0 °F - closed cup
flash_point_c
25 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
T Tanaka et al.
Nucleic acids research, 10(10), 3249-3260 (1982-05-25)
A simple procedure is described for synthesis of oligonucleotides by phosphate chemistry. Chains can be constructed rapidly with minimal equipment (a syringe and reagent bottles). The method is illustrated by synthesis of d-TGCAGGTT. Pertinent supporting data on the effect of
Synthetic Communications, 22, 289-289 (1992)
Synthesis and enantioselective aldol reaction of a chiral 2-oxo-2-propionyl-1, 3, 2-oxazaphosphorinane.
Gordon NJ and Evans Jr SA.
The Journal of Organic Chemistry, 58(20), 5295-5297 (1993)
Nanyan Fu et al.
Journal of peptide science : an official publication of the European Peptide Society, 12(4), 303-309 (2005-10-26)
A direct method for the preparation of phosphonamidate- and phosphonate-linked phosphonopeptides has been developed. Using this method, both phosphonopeptides were prepared in acceptable yields directly from simple and commercially available chemicals in one-pot reactions of benzyl carbamate, aldehydes, and methyl
Synthesis of deoxyoligonucleotides on a polymer support.
Matteucci MD and Caruthers MH.
Journal of the American Chemical Society, 103(11), 3181-3191 (1981)
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