235334
3,6-二硫杂-1,8-辛二醇
97%
别名:
2,2′-(乙烯二硫代)二乙醇, Lindlar 催化毒化剂
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关于此项目
线性分子式:
HO(CH2)2S(CH2)2S(CH2)2OH
化学文摘社编号:
分子量:
182.30
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
226-045-8
Beilstein/REAXYS Number:
1739193
MDL number:
Assay:
97%
产品名称
3,6-二硫杂-1,8-辛二醇, 97%
assay
97%
InChI key
PDHFSBXFZGYBIP-UHFFFAOYSA-N
InChI
1S/C6H14O2S2/c7-1-3-9-5-6-10-4-2-8/h7-8H,1-6H2
SMILES string
OCCSCCSCCO
bp
170 °C/0.5 mmHg (lit.)
mp
63-64 °C (lit.)
functional group
hydroxyl
thioether
Quality Level
Application
3,6-二硫代-1,8-辛二醇已用于：
- 作为外源螯合剂对膜可透过铜选择性荧光传感器进行评估，用于动态不稳定铜池的成像
- （+）-6-epi-粟树精胺和多羟基生物碱的不对称全合成
General description
3,6-二硫代-1,8-辛二醇是一种二级硫基催化剂毒剂。
存储类别
11 - Combustible Solids
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Asymmetric Total Synthesis of (+)-6-epi-Castanospermine by the Stereoselective Formation of a syn, anti Acetylenic 2-Amino-1, 3-diol Stereotriad.
Louvel J, et al.
European Journal of Organic Chemistry, 2010(15), 2921-2926 (2010)
Liuchun Yang et al.
Proceedings of the National Academy of Sciences of the United States of America, 102(32), 11179-11184 (2005-08-03)
Copper is an essential micronutrient that plays a central role for a broad range of biological processes. Although there is compelling evidence that the intracellular milieu does not contain any free copper ions, the rapid kinetics of copper uptake and
Eric J Stoner et al.
The Journal of organic chemistry, 68(23), 8847-8852 (2003-11-08)
Functionalized erythromycin 9-oxime derivatives are 6-O-allylated under mild conditions using substituted allyl tert-butyl carbonates under palladium(0) catalysis. This allylation works well where traditional ether-forming protocols function poorly. Allyl tert-butyl carbonates provide higher yields in this reaction than lesser substituted carbonates
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