235334
3,6-二硫杂-1,8-辛二醇
97%
别名:
2,2′-(乙烯二硫代)二乙醇, Lindlar 催化毒化剂
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关于此项目
线性分子式:
HO(CH2)2S(CH2)2S(CH2)2OH
化学文摘社编号:
分子量:
182.30
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
226-045-8
Beilstein/REAXYS Number:
1739193
MDL number:
产品名称
3,6-二硫杂-1,8-辛二醇, 97%
assay
97%
InChI key
PDHFSBXFZGYBIP-UHFFFAOYSA-N
InChI
1S/C6H14O2S2/c7-1-3-9-5-6-10-4-2-8/h7-8H,1-6H2
SMILES string
OCCSCCSCCO
bp
170 °C/0.5 mmHg (lit.)
mp
63-64 °C (lit.)
functional group
hydroxyl
thioether
Quality Level
Application
3,6-二硫代-1,8-辛二醇已用于：
- 作为外源螯合剂对膜可透过铜选择性荧光传感器进行评估，用于动态不稳定铜池的成像
- （+）-6-epi-粟树精胺和多羟基生物碱的不对称全合成
General description
3,6-二硫代-1,8-辛二醇是一种二级硫基催化剂毒剂。
存储类别
11 - Combustible Solids
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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Functionalized erythromycin 9-oxime derivatives are 6-O-allylated under mild conditions using substituted allyl tert-butyl carbonates under palladium(0) catalysis. This allylation works well where traditional ether-forming protocols function poorly. Allyl tert-butyl carbonates provide higher yields in this reaction than lesser substituted carbonates
Liuchun Yang et al.
Proceedings of the National Academy of Sciences of the United States of America, 102(32), 11179-11184 (2005-08-03)
Copper is an essential micronutrient that plays a central role for a broad range of biological processes. Although there is compelling evidence that the intracellular milieu does not contain any free copper ions, the rapid kinetics of copper uptake and
Asymmetric Total Synthesis of (+)-6-epi-Castanospermine by the Stereoselective Formation of a syn, anti Acetylenic 2-Amino-1, 3-diol Stereotriad.
Louvel J, et al.
European Journal of Organic Chemistry, 2010(15), 2921-2926 (2010)
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