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线性分子式:
(CH2N=CHC6H4OH)2
化学文摘社编号:
分子量:
268.31
EC Number:
202-376-3
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
Beilstein/REAXYS Number:
535296
MDL number:
Assay:
98%
InChI key
VEUMANXWQDHAJV-JYFOCSDGSA-N
InChI
1S/C16H16N2O2/c19-15-7-3-1-5-13(15)11-17-9-10-18-12-14-6-2-4-8-16(14)20/h1-8,11-12,19-20H,9-10H2/b17-11+,18-12+
SMILES string
Oc1ccccc1\C=N\CC\N=C\c2ccccc2O
assay
98%
mp
127-128 °C (lit.)
solubility
water: insoluble(lit.)
functional group
amine, imine
Quality Level
General description
在丙酮溶液中,N,N′-双(亚水杨基)乙二胺 (salen) 与氯化铁反应生成络合物 (Fe salen Cl)。
Application
采用 N,N′-双(亚水杨基)乙二胺 (salen) 为配位剂,以流动注射火焰原子吸收光谱法 (FI-AAS) 在线预浓缩铜和铅。
wgk
WGK 3
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
Hydration of epoxides on [CoIII salen)] encapsulated in silica-based nanoreactors.
Bo Li et al.
Angewandte Chemie (International ed. in English), 51(46), 11517-11521 (2012-10-16)
F Janati Fard et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 97, 74-82 (2012-07-04)
Co(III) salen complex with N,N'-dipyridoxyl (1,4-butanediamine) Schiff-base ligand as tetradentate ligand was synthesized and characterized by the elemental and spectroscopic analysis. The interaction of this complex with calf thymus DNA (ct DNA) has been investigated in vitro using UV absorption
Linus Chiang et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 18(44), 14117-14127 (2012-09-22)
Square-planar nickel(II) complexes of salen ligands, N,N'-bis(3-tert-butyl-(5R)-salicylidene)-1,2-cyclohexanediamine), in which R=tert-butyl (1), OMe (2), and NMe(2) (3), were prepared and the electronic structure of the one-electron-oxidized species [1-3](+·) was investigated in solution. Cyclic voltammograms of [1-3] showed two quasi-reversible redox waves
Structure and Paramagnetism of Five-and Six-Co-ordinate N: N' Bis-salicylidene Ethylenediamine Iron (III) Chloride.
Gerloch M, et al.
Nature, 212, 809-810 (1966)
Clare Bakewell et al.
Journal of the American Chemical Society, 134(51), 20577-20580 (2012-12-13)
Highly active yttrium phosphasalen initiators for the stereocontrolled ring-opening polymerization of rac-lactide are reported. The initiators are coordinated by a new class of ancillary ligand: an iminophosphorane derivative of the popular "salen" ligand, termed "phosphasalen". Changing the phosphasalen structure enables
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