236071
N,N′-双(亚水杨基)乙二胺
98%
别名:
N,N′-双水杨醛缩乙二胺, 二亚水杨基乙二胺
方案
98%
mp
127-128 °C (lit.)
溶解性
water: insoluble(lit.)
官能团
amine
imine
SMILES字符串
Oc1ccccc1\C=N\CC\N=C\c2ccccc2O
InChI
1S/C16H16N2O2/c19-15-7-3-1-5-13(15)11-17-9-10-18-12-14-6-2-4-8-16(14)20/h1-8,11-12,19-20H,9-10H2/b17-11+,18-12+
InChI key
VEUMANXWQDHAJV-JYFOCSDGSA-N
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一般描述
在丙酮溶液中,N,N′-双(亚水杨基)乙二胺 (salen) 与氯化铁反应生成络合物 (Fe salen Cl)。
应用
采用 N,N′-双(亚水杨基)乙二胺 (salen) 为配位剂,以流动注射火焰原子吸收光谱法 (FI-AAS) 在线预浓缩铜和铅。
警示用语:
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
David J Burns et al.
Organic & biomolecular chemistry, 10(38), 7666-7668 (2012-08-30)
Due to the lack of availability of unnatural (+)-quinic acid as a starting material, a 6-step synthesis of butane diacetal-protected (4S,5S)-dihydroxycyclohexen-1-one (formally derived from (+)-quinic acid) has been devised. The key catalytic asymmetric step involves a chiral Co-salen-catalysed epoxide ring-opening
Lakshmi Kanta Das et al.
Dalton transactions (Cambridge, England : 2003), 41(36), 11009-11017 (2012-08-04)
Two new trinuclear hetero-metallic copper(II)-zinc(II) complexes [(CuL)(2)Zn(N(3))(2)] (1A and 1B) have been synthesized using [CuL] as a so-called "metalloligand" (where H(2)L = N,N'-bis(salicylidene)-1,3-propanediamine) and structurally characterized. Complexes 1A and 1B have the same molecular formula but crystallize in different crystal
Immobilized salen (N,N'-bis (salicylidene) ethylenediamine) as a complexing agent for on-line sorbent extraction/preconcentration and flow injection-flame atomic absorption spectrometry.
Dadfarnia S, et al.
Analytica Chimica Acta, 539(1), 69-75 (2005)
Teng Zhang et al.
Chemical communications (Cambridge, England), 48(70), 8766-8768 (2012-07-28)
Chiral metal-organic frameworks built from a Co-salen derived dicarboxylate bridging ligand exhibited different regioselectivities from the corresponding homogeneous catalyst by shutting down bimolecular activation pathways.
Mohammad Azam et al.
Dalton transactions (Cambridge, England : 2003), 41(35), 10854-10864 (2012-08-04)
We have reported the synthesis of a novel salen ligand and its mononuclear Pd-salen complexes derived from 2-{[2-hydroxy-3-{[(E)-(2-hydroxyphenyl)methylidene]amino}propyl)imino]methyl}phenol. The newly synthesized and isolated Pd(II) complexes have been identified and fully characterized by various physico-chemical studies viz., elemental analyses, IR, UV-Vis
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