236233
N-甲基苯胺
≥99%
别名:
一甲基苯胺
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关于此项目
线性分子式:
C6H5NHCH3
化学文摘社编号:
分子量:
107.15
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
202-870-9
Beilstein/REAXYS Number:
741982
MDL number:
产品名称
N-甲基苯胺, ≥99%
InChI key
AFBPFSWMIHJQDM-UHFFFAOYSA-N
InChI
1S/C7H9N/c1-8-7-5-3-2-4-6-7/h2-6,8H,1H3
SMILES string
CNc1ccccc1
assay
≥99%
form
liquid
refractive index
n20/D 1.571 (lit.)
bp
196 °C (lit.)
mp
−57 °C (lit.)
solubility
water: slightly soluble 30 g/L
alcohol: soluble(lit.)
diethyl ether: soluble(lit.)
density
0.989 g/mL at 25 °C (lit.)
functional group
amine
Quality Level
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Application
N-Methylaniline (NMA) was used in the preparation of self-assembled poly(N-methylaniline)-lignosulfonate (PNMA-LS) composite spheres with reactive silver-ion adsorbability. NMA was also used in electrodeposition of poly(N-methylaniline) (PNMA) coatings on a steel disc electrode using potentiodynamic, potentiostatic and galvanostatic techniques.
General description
Chemical oxidation of N-methylaniline with dichromate (oxidant) has been studied by Raman spectroscopy.
signalword
Danger
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - STOT RE 2 Oral
target_organs
Liver,spleen,Bone marrow
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
185.0 °F - closed cup
flash_point_c
85 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Qiu-Feng Lü et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 19(33), 10935-10944 (2013-07-03)
Self-assembled poly(N-methylaniline)-lignosulfonate (PNMA-LS) composite spheres with reactive silver-ion adsorbability were prepared from N-methylaniline by using lignosulfonate (LS) as a dispersant. The results show that the PNMA-LS composite consisted of spheres with good size distribution and an average diameter of 1.03-1.27
Electropolymerization of poly (N-methylaniline) on mild steel: Synthesis, characterization and corrosion protection.
Yag?an A, et al.
Journal of Electroanalytical Chemistry, 578(2), 231-238 (2005)
Dongmei Li et al.
Dalton transactions (Cambridge, England : 2003), (2)(2), 291-297 (2008-12-18)
The mechanism of N-dealkylation of N-cyclopropyl-N-methylaniline () catalyzed by cytochrome P450 (P450) was investigated using density functional theory. This reaction involves two steps. The first one is a Calpha-H hydroxylation on the N-substituent to form a carbinolaniline complex, and the
Jonathan L Sessler et al.
Chemical communications (Cambridge, England), (14)(14), 1892-1894 (2005-03-30)
A novel porphyrin-fullerene dyad assembled through Watson-Crick hydrogen bonds is described; this system undergoes photoinduced electron transfer upon irradiation with visible light to produce a charge separated state that is substantially longer lived than that of previous dyads of this
Israel González et al.
Organic letters, 11(8), 1677-1680 (2009-04-10)
N-Methylanilines are readily synthesized in high yields through the copper(II)-promoted coupling of anilines and methylboronic acid. This method represents a new approach for the selective monomethylation of anilines, and it is the first reported example of a Chan-Lam coupling involving
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