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Merck
CN

236306

烯丙基氯

ReagentPlus®, 99%

别名:

3-氯-1-丙烯, 氯丙烯

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线性分子式:
CH2=CHCH2Cl
化学文摘社编号:
107-05-1
分子量:
76.52
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24854161
EC Number:
203-457-6
Beilstein/REAXYS Number:
635704
MDL number:
MFCD00000984

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产品名称

烯丙基氯, ReagentPlus®, 99%

InChI key

OSDWBNJEKMUWAV-UHFFFAOYSA-N

InChI

1S/C3H5Cl/c1-2-3-4/h2H,1,3H2

SMILES string

ClCC=C

vapor density

2.6 (vs air)

vapor pressure

20.58 psi ( 55 °C)
5.71 psi ( 20 °C)

product line

ReagentPlus®

assay

99%

form

liquid

expl. lim.

11.2 %

refractive index

n20/D 1.414 (lit.)

bp

44-46 °C (lit.)

mp

−130 °C (lit.)

solubility

alcohol: miscible(lit.)
chloroform: miscible(lit.)
diethyl ether: miscible(lit.)
petroleum ether: miscible(lit.)
water: slightly soluble(lit.)

density

0.939 g/mL at 25 °C (lit.)

functional group

alkyl halide
chloro

storage temp.

2-8°C

Quality Level

100

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相关类别

Application

氯丙烯：
  • 已用作 193 nm 激光闪光光解产生烯丙基自由基的前体
  • 已用于 α,ω-双官能团化学中间体的合成（通过 交叉复分解反应）

General description

氯丙烯与过氧化氢环氧化的动力学过程已有报道 。

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

signalword

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Muta. 2 - Skin Irrit. 2 - STOT RE 2 - STOT SE 3

target_organs

Nervous system,Liver,Kidney, Respiratory system

存储类别

3 - Flammable liquids

wgk

WGK 2

flash_point_f

-25.6 °F

flash_point_c

-32 °C

ppe

Eyeshields, Faceshields, Gloves

法规信息

危险化学品
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCT2334
MKCT2335
STBK3883
STBJ4696
MKCL0865

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Epoxidation of allyl chloride with hydrogen peroxide catalyzed by titanium silicalite 1.
Gao H, et al.
Applied Catalysis A: General, 138(1), 27-38 (1996)
Cross-metathesis reactions of allyl chloride with fatty acid methyl esters: Efficient synthesis of a, ?-difunctional chemical intermediates from renewable raw materials.
Jacobs T, et al.
Applied Catalysis A: General, 353(1), 32-35 (2009)
Lars Seidel et al.
Molecules (Basel, Switzerland), 18(11), 13608-13622 (2013-11-07)
Photochemically driven reactions involving unsaturated radicals produce a thick global layer of organic haze on Titan, Saturn's largest moon. The allyl radical self-reaction is an example for this type of chemistry and was examined at room temperature from an experimental
Ti Ouyang et al.
The journal of physical chemistry. B, 110(11), 5611-5620 (2006-03-17)
The adsorption of allyl alcohol, acrylic acid, and allyl chloride, as well as unsaturated organic molecules such as acetylene and 1,3 butadiene, on reconstructed diamond (100) 2 x 1 have been investigated using high-resolution electron energy loss (HREELS) spectroscopy and
B M de Rooij et al.
Occupational and environmental medicine, 54(9), 653-661 (1998-01-10)
To evaluate the use of urinary mercapturic acids as a biomarker of human exposure to allyl chloride (3-chloropropene) (AC). During three regular shut down periods in a production factory for AC, both types of variables were measured in 136 workers
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