Merck
CN

236454

Sigma-Aldrich

邻氨基苯甲酸甲酯

ReagentPlus®, ≥99%

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别名:
邻氨基苯甲酸甲酯
线性分子式:
2-(H2N)C6H4CO2CH3
CAS号:
分子量:
151.16
Beilstein:
606965
EC 号:
MDL编号:
PubChem化学物质编号:
NACRES:
NA.22

蒸汽压

1 mmHg ( 20 °C)

质量水平

产品线

ReagentPlus®

检测方案

≥99%

形式

liquid

自燃温度

986 °F

折射率

n20/D 1.582 (lit.)

bp

256 °C (lit.)

mp

24 °C (lit.)

溶解性

alcohol: freely soluble(lit.)
diethyl ether: freely soluble(lit.)
water: slightly soluble(lit.)

密度

1.168 g/mL at 25 °C (lit.)

SMILES string

COC(=O)c1ccccc1N

InChI

1S/C8H9NO2/c1-11-8(10)6-4-2-3-5-7(6)9/h2-5H,9H2,1H3

InChI key

VAMXMNNIEUEQDV-UHFFFAOYSA-N

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此商品
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Methyl 2-aminobenzoate ReagentPlus®, ≥99%

Sigma-Aldrich

236454

邻氨基苯甲酸甲酯

Methyl anthranilate ≥98%, FCC, FG

Sigma-Aldrich

W268208

邻氨基苯甲酸甲酯

Methyl anthranilate natural, ≥98%, FG

Sigma-Aldrich

W268224

邻氨基苯甲酸甲酯

Ethyl 2-aminobenzoate ≥96%, FCC, FG

Sigma-Aldrich

W242101

2-氨基苯甲酸乙酯

form

liquid

form

-

form

-

form

-

refractive index

n20/D 1.582 (lit.)

refractive index

n20/D 1.582 (lit.)

refractive index

n20/D 1.582 (lit.)

refractive index

n20/D 1.564 (lit.)

bp

256 °C (lit.)

bp

256 °C (lit.)

bp

256 °C (lit.)

bp

129-130 °C/9 mmHg (lit.)

mp

24 °C (lit.)

mp

24 °C (lit.)

mp

24 °C (lit.)

mp

13-15 °C (lit.)

solubility

alcohol: freely soluble(lit.), diethyl ether: freely soluble(lit.), water: slightly soluble(lit.)

solubility

-

solubility

-

solubility

-

一般描述

2-氨基苯甲酸甲酯在140°C下可与2,4-(4-甲氧基苯基)-1,3,2,4-二硫代二膦-2,4-二硫化物反应生成1,2-二氢-2-(甲氧基苯基)-4H-3,1,2-苯并噻唑磷酰-4-硫酮-2-硫化物和4-甲氧基苯基三硫代磷酸二甲酯

应用

2-氨基苯甲酸甲酯已被用于合成新型4-氯-2-巯基苯磺酰胺衍生物

法律信息

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Eye Irrit. 2

储存分类代码

10 - Combustible liquids

WGK

WGK 1

闪点(°F)

262.4 °F - closed cup

闪点(°C)

128 °C - closed cup

个人防护装备

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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4-氨基苯甲酸乙酯

Studies on organophosphorus compounds-XXXVI: simple new routes to phosphorins from 2-hydroxy-, 2-mercapto-, and 2-aminobenzoic acids and their derivatives.
El-Barbary AA and Lawesson S-O.
Tetrahedron, 37(15), 2641-2646 (1981)
Yuriko Ito et al.
Journal of agricultural and food chemistry, 50(17), 4878-4884 (2002-08-09)
The odorants in Chinese jasmine green tea scented with jasmine flowers (Jasminum sambac) were separated from the infusion by adsorption to Porapak Q resin. Among the 66 compounds identified by GC and GC/MS, linalool (floral), methyl anthranilate (grape-like), 4-hexanolide (sweet)
Marcus Taupp et al.
Journal of agricultural and food chemistry, 53(24), 9586-9589 (2005-11-24)
Bacillus megaterium, isolated in a screening process from topsoil, was used for N-demethylation of natural N-methyl methyl anthranilate to produce natural methyl anthranilate. Maximal productivity of 70 mg/L/day was achieved under laboratory-scale conditions without further optimization. No byproducts were observed.
Chris E Houlden et al.
Angewandte Chemie (International ed. in English), 48(10), 1830-1833 (2009-01-27)
Pd and CO--ureally got me! The title reaction proceeds efficiently at 18 degrees C under CO (1 atm) with 5 % [Pd(OTs)(2)(MeCN)(2)] as precatalyst. Depending on the solvents used, either anthranilates or cyclic imides can be obtained in high yields
T H Burne et al.
Physiology & behavior, 62(6), 1299-1302 (1998-01-07)
The relative importance of taste and odour cues in a one-trial passive avoidance learning (PAL) task was examined. One-day-old chicks were presented with a small bead and different combinations of the taste and odour of methyl anthranilate (MeA). The chicks

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