236454
邻氨基苯甲酸甲酯
ReagentPlus®, ≥99%
别名:
邻氨基苯甲酸甲酯
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关于此项目
线性分子式:
2-(H2N)C6H4CO2CH3
化学文摘社编号:
分子量:
151.16
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
205-132-4
Beilstein/REAXYS Number:
606965
MDL number:
产品名称
邻氨基苯甲酸甲酯, ReagentPlus®, ≥99%
InChI key
VAMXMNNIEUEQDV-UHFFFAOYSA-N
InChI
1S/C8H9NO2/c1-11-8(10)6-4-2-3-5-7(6)9/h2-5H,9H2,1H3
SMILES string
COC(=O)c1ccccc1N
vapor pressure
1 mmHg ( 20 °C)
product line
ReagentPlus®
assay
≥99%
form
liquid
autoignition temp.
986 °F
refractive index
n20/D 1.582 (lit.)
bp
256 °C (lit.)
mp
24 °C (lit.)
solubility
alcohol: freely soluble(lit.)
diethyl ether: freely soluble(lit.)
water: slightly soluble(lit.)
density
1.168 g/mL at 25 °C (lit.)
functional group
ester
Quality Level
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Application
2-氨基苯甲酸甲酯已被用于合成新型4-氯-2-巯基苯磺酰胺衍生物。
General description
2-氨基苯甲酸甲酯在140°C下可与2,4-双（4-甲氧基苯基）-1,3,2,4-二硫代二膦-2,4-二硫化物反应生成1,2-二氢-2-（对甲氧基苯基）-4H-3,1,2-苯并噻唑磷酰-4-硫酮-2-硫化物和4-甲氧基苯基三硫代磷酸二甲酯。
Legal Information
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
Hazard Classifications
Eye Irrit. 2
signalword
Warning
hcodes
存储类别
10 - Combustible liquids
wgk
WGK 1
flash_point_f
262.4 °F - closed cup
flash_point_c
128 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Studies on organophosphorus compounds-XXXVI: simple new routes to phosphorins from 2-hydroxy-, 2-mercapto-, and 2-aminobenzoic acids and their derivatives.
El-Barbary AA and Lawesson S-O.
Tetrahedron, 37(15), 2641-2646 (1981)
Chris E Houlden et al.
Angewandte Chemie (International ed. in English), 48(10), 1830-1833 (2009-01-27)
Pd and CO--ureally got me! The title reaction proceeds efficiently at 18 degrees C under CO (1 atm) with 5 % [Pd(OTs)(2)(MeCN)(2)] as precatalyst. Depending on the solvents used, either anthranilates or cyclic imides can be obtained in high yields
T H Burne et al.
Physiology & behavior, 62(6), 1299-1302 (1998-01-07)
The relative importance of taste and odour cues in a one-trial passive avoidance learning (PAL) task was examined. One-day-old chicks were presented with a small bead and different combinations of the taste and odour of methyl anthranilate (MeA). The chicks
Marcus Taupp et al.
Journal of agricultural and food chemistry, 53(24), 9586-9589 (2005-11-24)
Bacillus megaterium, isolated in a screening process from topsoil, was used for N-demethylation of natural N-methyl methyl anthranilate to produce natural methyl anthranilate. Maximal productivity of 70 mg/L/day was achieved under laboratory-scale conditions without further optimization. No byproducts were observed.
N R Lien et al.
Carbohydrate research, 344(18), 2606-2608 (2009-11-03)
A 2:1 complex between cyclomaltoheptaose (beta-cyclodextrin) and N-methylanthranilic acid has been studied in the solid state. The inclusion complex belongs to the triclinic system (space group P1) with unit cell dimensions a=15.2773(15)A, b=15.4710(15)A, c=17.9627(18)A, alpha=99.632(5) degrees , beta=113.416(5) degrees
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