assay
99%
form
solid
optical activity
[α]25/D −49.8°, c = 2 in H2O
bp
120-122 °C/15 mmHg (lit.)
mp
91 °C (lit.)
functional group
ester, hydroxyl
SMILES string
CC1(C)COC(=O)[C@@H]1O
InChI
1S/C6H10O3/c1-6(2)3-9-5(8)4(6)7/h4,7H,3H2,1-2H3/t4-/m0/s1
InChI key
SERHXTVXHNVDKA-BYPYZUCNSA-N
Application
D-(-)-泛内酯是多种不对称合成反应中使用的手性助剂。
它可用作合成以下物质的手性原料:
它可用作合成以下物质的手性原料:
- 昆虫性信息素 1S,2S,3R-1-乙酰氧基甲基--2,3,4,4-四甲基环戊烷。
- (R)-8-羟基-4,7,7-三甲基-7,8-二氢环戊基[e]异吲哚-1,3(2H,6H)-二酮的(-)-对映异构体, 其是一种倍半萜烯生物碱。
- 一种名为isofregenedadiol的双环二萜。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2
存储类别
11 - Combustible Solids
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Total synthesis of an anticancer norsesquiterpene alkaloid isolated from the fungus Flammulina velutipes
Kashinath K, et al.
Organic & Biomolecular Chemistry, 12(24), 4098-4103 (2014)
Enantiospecific synthesis of sex pheromone of the obscure mealybug from pantolactone via tandem conjugate addition/cyclization
Hajare AK, et al.
Tetrahedron Letters, 51(40), 5291-5293 (2010)
Asymmetric diels alder reactions and michael type additions with 6 (R)-3′(R)-Pantolactone-substituted-2H-pyran-3 (6H)-one.
Knol J, et al.
Tetrahedron Letters, 32(50), 7465-7468 (1991)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 237817-25G | 04061838786265 |
| 237817-5G | 04061838786272 |
