产品名称
1,2-二碘苯, 98%
InChI key
BBOLNFYSRZVALD-UHFFFAOYSA-N
InChI
1S/C6H4I2/c7-5-3-1-2-4-6(5)8/h1-4H
SMILES string
Ic1ccccc1I
assay
98%
form
liquid
refractive index
n20/D 1.718 (lit.)
bp
152 °C/15 mmHg (lit.)
density
2.524 g/mL at 25 °C (lit.)
functional group
iodo
storage temp.
2-8°C
Quality Level
Application
1,2-二碘苯已用于制备嘌呤[8,9-f]菲啶。
General description
目前业内已研究了环己烷、呋喃,苯和含四苯基环戊二烯酮的苯中的1,2-二碘苯光解。
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
The Photolysis of 1, 2-Diiodobenzene: A Photochemical Source of Benzyne.
Kampmeier JA and Hoffmeister E.
Journal of the American Chemical Society, 84(19), 3787-3788 (1962)
Igor Cerna et al.
The Journal of organic chemistry, 75(7), 2302-2308 (2010-03-05)
Intramolecular C-H arylations were employed as a key step in the synthesis of hitherto unknown fused purine systems: 13-substituted purino[8,9-f]phenanthridines and 11-substituted 5,6-dihydropurino[8,9-a]isoquinolines. The purino[8,9-f]phenanthridines were prepared in moderate yields by double C-H arylations of 9-phenylpurines with 1,2-diiodobenzene or, more
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