238252
1-碘癸烷
98%
别名:
癸基碘
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关于此项目
线性分子式:
CH3(CH2)9I
化学文摘社编号:
分子量:
268.18
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
218-104-1
Beilstein/REAXYS Number:
1735228
MDL number:
Assay:
98%
Form:
liquid
InChI key
SKIDNYUZJPMKFC-UHFFFAOYSA-N
InChI
1S/C10H21I/c1-2-3-4-5-6-7-8-9-10-11/h2-10H2,1H3
SMILES string
CCCCCCCCCCI
vapor density
>5 (vs air)
vapor pressure
0.01 mmHg ( 20 °C)
assay
98%
form
liquid
contains
copper as stabilizer
refractive index
n20/D 1.485 (lit.)
bp
132 °C/15 mmHg (lit.)
density
1.257 g/mL at 25 °C (lit.)
functional group
alkyl halide, iodo
Quality Level
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Application
1-Iododecane has been used in the preparation of 9-nonadecanone via palladium-catalyzed carbonylative cross-coupling reaction with 9-octyl-9-borabicyclo[3.3.l]nonane.
General description
Electrochemical reduction of 1-iododecane at mercury cathodes in DMF containing tetra-n-butylammonium perchlorate or tetramethyl ammonium perchlorate (supporting electrolyte) has been investigated.
wgk
WGK 3
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
flash_point_f
230.0 °F - closed cup
flash_point_c
110 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Electrochemical reduction of 1-iododecane and 1-bromodecane at a mercury cathode in dimethylformamide.
McNamee GM, et al.
Journal of the American Chemical Society, 99(6), 1831-1835 (1977)
Palladium-catalyzed carbonylative cross-coupling reaction of iodoalkanes with 9-alkyl-9-BBN derivatives. A direct and selective synthesis of ketones.
Ishiyama T and Miyaura N.
Tetrahedron Letters, 32(47), 6923-6926 (1991)
María José Sosa et al.
Photochemistry and photobiology, 97(1), 80-90 (2020-07-07)
Mono- and bis-decylated lumazines have been synthesized and characterized. Namely, mono-decyl chain [1-decylpteridine-2,4(1,3H)-dione] 6a and bis-decyl chain [1,3-didecylpteridine-2,4(1,3H)-dione] 7a conjugates were synthesized by nucleophilic substitution (SN 2) reactions of lumazine with 1-iododecane in N,N-dimethylformamide (DMF) solvent. Decyl chain coupling occurred
Niluksha Walalawela et al.
Photochemistry and photobiology, 95(5), 1160-1168 (2019-03-19)
In order to develop a new long alkane chain pterin that leaves the pterin core largely unperturbed, we synthesized and photochemically characterized decyl pterin-6-carboxyl ester (CapC) that preserves the pterin amide group. CapC contains a decyl-chain at the carboxylic acid
Anthony N Cauley et al.
Biomaterials science, 5(10), 2114-2121 (2017-08-24)
We report a library of functionalized lignins and demonstrate their utility as nanocontainers for organic dyes in biologically relevant applications. Kraft lignin was modified via S
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