238287
1-碘己烷
contains copper as stabilizer, ≥98%
别名:
己基碘
质量水平
方案
≥98%
表单
liquid
包含
copper as stabilizer
折射率
n20/D 1.492 (lit.)
沸点
179-180 °C (lit.)
密度
1.437 g/mL at 25 °C (lit.)
官能团
alkyl halide
iodo
SMILES字符串
CCCCCCI
InChI
1S/C6H13I/c1-2-3-4-5-6-7/h2-6H2,1H3
InChI key
ANOOTOPTCJRUPK-UHFFFAOYSA-N
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一般描述
1-碘代己烷与 9-辛基-9-硼杂双环发生钯催化的交叉偶联反应 [3.3.l] 壬烷给十四烷。用程序升温脱附和 X 射线光电子能谱研究了 1-碘代己烷在 Ni (100) 单晶表面上的热反应。
警示用语：
Warning
危险声明
危险分类
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
141.8 °F - closed cup
闪点(°C)
61 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Thermal Reactions of Alkyl Iodides on Ni (100) Single Crystal Surfaces.
Tjandra S and Zaera F.
Journal of the American Chemical Society, 117(38), 9749-9755 (1995)
Palladium-catalyzed carbonylative cross-coupling reaction of iodoalkanes with 9-alkyl-9-BBN derivatives. A direct and selective synthesis of ketones.
Ishiyama T and Miyaura N.
Tetrahedron Letters, 32(47), 6923-6926 (1991)
Martha Kafetzi et al.
Polymers, 13(3) (2021-01-27)
In this work, the synthesis and the aqueous solution self-assembly behavior of novel partially hydrophobically modified poly(2-(dimethylamino) ethyl methacrylate)-b-poly(oligo(ethylelene glycol) methyl ether methacrylatetabel) pH and temperature responsive random diblock copolymers (P(DMAEMA-co-Q6/12DMAEMA)-b-POEGMA), are reported. The chemical modifications were accomplished via quaternization
Robert Löwe et al.
Molecules (Basel, Switzerland), 24(2) (2019-01-20)
Eight new polymerizable ammonium-TFSI ionic liquids were synthesized and characterized with respect to an application in energy storage devices. The ionic liquids feature methacrylate or acrylate termination as polymerizable groups. The preparation was optimized to obtain the precursors and ionic
Barbara Nozière et al.
Angewandte Chemie (International ed. in English), 58(39), 13976-13982 (2019-07-31)
The autoxidation of organic peroxy radicals (RO2 ) into hydroperoxy-alkyl radicals (QOOH), then hydroperoxy-peroxy radicals (HOOQO2 ) is now considered to be important in the Earth's atmosphere. To avoid mechanistic uncertainties these reactions are best studied by monitoring the radicals.
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