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238325

烯丙基碘

Name: 烯丙基碘
Brand: ALDRICH

98%

别名:

3-碘-1-丙烯

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关于此项目

线性分子式:

CH₂=CHCH₂I

化学文摘社编号:

556-56-9

分子量:

167.98

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24854295

EC Number:

209-130-4

Beilstein/REAXYS Number:

1697594

MDL number:

MFCD00001094

Assay:

98%

Form:

liquid

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属性

Quality Level

100

assay

98%

form

liquid

contains

copper as stabilizer

refractive index

n20/D 1.554 (lit.)

bp

102-103 °C (lit.)

solubility

alcohol: miscible(lit.), chloroform: miscible(lit.), diethyl ether: miscible(lit.), water: insoluble (practically)(lit.)

density

1.837 g/mL at 25 °C (lit.)

functional group

alkyl halide, iodo

storage temp.

2-8°C

SMILES string

ICC=C

InChI

1S/C3H5I/c1-2-3-4/h2H,1,3H2

InChI key

HFEHLDPGIKPNKL-UHFFFAOYSA-N

说明

General description

研究了在 270～480℃ 温度范围内，烯丙基碘化物与 MoO₃, Bi₂O₃和 Bi、Co、Mg 的钼酸盐的相互作用。

Application

使用的烯丙基碘为：

气相色谱法研究烯丙基化合物在单脉冲激波管中的复合
在环丙烯的顺式-双烯丙基化反应中与烯丙基倍半碘化钠配合使用的试剂

pictograms

GHS02,GHS06,GHS05

signalword

Danger

hcodes

H225,H300,H314

pcodes

P210 - P233 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 2 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B

存储类别

3 - Flammable liquids

wgk

WGK 1

flash_point_f

60.8 °F - closed cup

flash_point_c

16 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

危险化学品

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历史批次信息供参考:

分析证书(COA)

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Interaction of allyl iodide with molybdate catalysts for the selective oxidation of hydrocarbons.

Grzybowska B, et al.

J. Catal., 49(2), 150-163 (1977)

Single pulse shock tube study of allyl radical recombination.

Aleksandr Fridlyand et al.

The journal of physical chemistry. A, 117(23), 4762-4776 (2013-05-18)

The recombination and disproportionation of allyl radicals has been studied in a single pulse shock tube with gas chromatographic measurements at 1-10 bar, 650-1300 K, and 1.4-2 ms reaction times. 1,5-Hexadiene and allyl iodide were used as precursors. Simulation of

Relative Reactivities of Three Isomeric Aromatic Biradicals with a 1,4-Biradical Topology Are Controlled by Polar Effects.

Xin Ma et al.

Chemistry (Weinheim an der Bergstrasse, Germany), 25(25), 6355-6361 (2019-02-28)

Unexpectedly, the 5-dehydroquinoline radical cation was formed in the gas phase from the 5-iodo-8-nitroquinolinium cation upon ion-trap collision-activated dissociation. This reaction involves the cleavage of a nitro group to generate an intermediate monoradical, namely, the 8-dehydro-5-iodoquinolinium cation, followed by rearrangement

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全球贸易项目编号

货号	GTIN
238325-100G	04061838786852
238325-25G	04061838786869