238325
烯丙基碘
98%
别名:
3-碘-1-丙烯
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关于此项目
线性分子式:
CH2=CHCH2I
化学文摘社编号:
分子量:
167.98
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
209-130-4
Beilstein/REAXYS Number:
1697594
MDL number:
Assay:
98%
Form:
liquid
产品名称
烯丙基碘, 98%
InChI key
HFEHLDPGIKPNKL-UHFFFAOYSA-N
InChI
1S/C3H5I/c1-2-3-4/h2H,1,3H2
SMILES string
ICC=C
assay
98%
form
liquid
contains
copper as stabilizer
refractive index
n20/D 1.554 (lit.)
bp
102-103 °C (lit.)
solubility
alcohol: miscible(lit.)
chloroform: miscible(lit.)
diethyl ether: miscible(lit.)
water: insoluble (practically)(lit.)
density
1.837 g/mL at 25 °C (lit.)
functional group
alkyl halide
iodo
storage temp.
2-8°C
Quality Level
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Application
使用的烯丙基碘为：
- 气相色谱法研究烯丙基化合物在单脉冲激波管中的复合
- 在环丙烯的顺式-双烯丙基化反应中与烯丙基倍半碘化钠配合使用的试剂
General description
研究了在 270～480℃ 温度范围内，烯丙基碘化物与 MoO3, Bi2O3和 Bi、Co、Mg 的钼酸盐的相互作用。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 2 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B
存储类别
3 - Flammable liquids
wgk
WGK 1
flash_point_f
60.8 °F - closed cup
flash_point_c
16 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Tsunehisa Hirashita et al.
Organic & biomolecular chemistry, 5(13), 2154-2158 (2007-06-22)
The successive double allylation of cyclopropenes with allylindium sesquiiodide and allyl iodide proceeded with a cis-addition mode in the presence of other organometallics (e.g. Grignard reagent, cuprate, Et(2)Zn and Et(3)Al), giving the corresponding cis-diallylcyclopropanes in high yields.
Interaction of allyl iodide with molybdate catalysts for the selective oxidation of hydrocarbons.
Grzybowska B, et al.
J. Catal., 49(2), 150-163 (1977)
Aleksandr Fridlyand et al.
The journal of physical chemistry. A, 117(23), 4762-4776 (2013-05-18)
The recombination and disproportionation of allyl radicals has been studied in a single pulse shock tube with gas chromatographic measurements at 1-10 bar, 650-1300 K, and 1.4-2 ms reaction times. 1,5-Hexadiene and allyl iodide were used as precursors. Simulation of
Xin Ma et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 25(25), 6355-6361 (2019-02-28)
Unexpectedly, the 5-dehydroquinoline radical cation was formed in the gas phase from the 5-iodo-8-nitroquinolinium cation upon ion-trap collision-activated dissociation. This reaction involves the cleavage of a nitro group to generate an intermediate monoradical, namely, the 8-dehydro-5-iodoquinolinium cation, followed by rearrangement
Michael Lesslie et al.
European journal of mass spectrometry (Chichester, England), 21(3), 589-597 (2015-08-27)
Radical migration, both intramolecular and intermolecular, from the tyrosine phenoxyl radical Tyr(O(∙)) to the cysteine radical Cys(S(∙)) in model peptide systems was observed in the gas phase. Ion-molecule reactions (IMRs) between the radical cation of homotyrosine and propyl thiol resulted
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