238325
烯丙基碘
98%
别名:
3-碘-1-丙烯
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关于此项目
线性分子式:
CH2=CHCH2I
化学文摘社编号:
分子量:
167.98
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
209-130-4
Beilstein/REAXYS Number:
1697594
MDL number:
Assay:
98%
Form:
liquid
InChI key
HFEHLDPGIKPNKL-UHFFFAOYSA-N
InChI
1S/C3H5I/c1-2-3-4/h2H,1,3H2
SMILES string
ICC=C
assay
98%
form
liquid
contains
copper as stabilizer
Quality Level
bp
102-103 °C (lit.)
solubility
alcohol: miscible(lit.), chloroform: miscible(lit.), diethyl ether: miscible(lit.), water: insoluble (practically)(lit.)
density
1.837 g/mL at 25 °C (lit.)
functional group
alkyl halide, iodo
storage temp.
2-8°C
General description
研究了在 270～480℃ 温度范围内，烯丙基碘化物与 MoO3, Bi2O3和 Bi、Co、Mg 的钼酸盐的相互作用。
Application
使用的烯丙基碘为：
- 气相色谱法研究烯丙基化合物在单脉冲激波管中的复合
- 在环丙烯的顺式-双烯丙基化反应中与烯丙基倍半碘化钠配合使用的试剂
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 2 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B
存储类别
3 - Flammable liquids
wgk
WGK 1
flash_point_f
60.8 °F - closed cup
flash_point_c
16 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Interaction of allyl iodide with molybdate catalysts for the selective oxidation of hydrocarbons.
Grzybowska B, et al.
J. Catal., 49(2), 150-163 (1977)
Tsunehisa Hirashita et al.
Organic & biomolecular chemistry, 5(13), 2154-2158 (2007-06-22)
The successive double allylation of cyclopropenes with allylindium sesquiiodide and allyl iodide proceeded with a cis-addition mode in the presence of other organometallics (e.g. Grignard reagent, cuprate, Et(2)Zn and Et(3)Al), giving the corresponding cis-diallylcyclopropanes in high yields.
Aleksandr Fridlyand et al.
The journal of physical chemistry. A, 117(23), 4762-4776 (2013-05-18)
The recombination and disproportionation of allyl radicals has been studied in a single pulse shock tube with gas chromatographic measurements at 1-10 bar, 650-1300 K, and 1.4-2 ms reaction times. 1,5-Hexadiene and allyl iodide were used as precursors. Simulation of
Xin Ma et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 25(25), 6355-6361 (2019-02-28)
Unexpectedly, the 5-dehydroquinoline radical cation was formed in the gas phase from the 5-iodo-8-nitroquinolinium cation upon ion-trap collision-activated dissociation. This reaction involves the cleavage of a nitro group to generate an intermediate monoradical, namely, the 8-dehydro-5-iodoquinolinium cation, followed by rearrangement
Michael Lesslie et al.
European journal of mass spectrometry (Chichester, England), 21(3), 589-597 (2015-08-27)
Radical migration, both intramolecular and intermolecular, from the tyrosine phenoxyl radical Tyr(O(∙)) to the cysteine radical Cys(S(∙)) in model peptide systems was observed in the gas phase. Ion-molecule reactions (IMRs) between the radical cation of homotyrosine and propyl thiol resulted
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