240532
烯丙醇
≥99%, liquid
别名:
2-丙烯-1-醇
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关于此项目
线性分子式:
CH2=CHCH2OH
化学文摘社编号:
分子量:
58.08
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
203-470-7
MDL number:
Beilstein/REAXYS Number:
605307
产品名称
烯丙醇, ≥99%
InChI key
XXROGKLTLUQVRX-UHFFFAOYSA-N
InChI
1S/C3H6O/c1-2-3-4/h2,4H,1,3H2
SMILES string
OCC=C
vapor density
2 (vs air)
vapor pressure
23.8 mmHg ( 25 °C)
assay
≥99%
form
liquid
autoignition temp.
712 °F
expl. lim.
18 %
refractive index
n20/D 1.412 (lit.)
bp
96-98 °C (lit.)
mp
−129 °C (lit.)
solubility
alcohol: miscible(lit.)
chloroform: miscible(lit.)
diethyl ether: miscible(lit.)
water: miscible(lit.)
density
0.854 g/mL at 25 °C (lit.)
functional group
hydroxyl
Quality Level
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Application
使用Pd/TiO2 催化烯丙醇发生光催化转移氢解反应，可制备丙烯。
烯丙醇被用于酵母菌（Saccharomyces cerevisiae）培养中。
用于诱导肝脏损坏的小鼠模型，该模型用于研究肝细胞毒性和肝干细胞介导修复的机制。
General description
烯丙醇在预吸附氧的金表面上的部分氧化已被研究。
烯丙醇是工业上重要的烯醇。它是合成各种烯丙基衍生物的原料，如烯丙基二甘醇二碳酸酯、烯丙基缩水甘油醚、1,4-丁二醇和聚(苯乙烯-烯丙醇)等。这些衍生物可用于镜片、偶联剂、增塑剂、交联剂和涂料添加剂中。烯丙醇可以通过铼催化的甘油脱氧脱水反应进行制备。
signalword
Danger
Hazard Classifications
Acute Tox. 2 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 3 - Eye Irrit. 2 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
71.6 °F - closed cup
flash_point_c
22 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
监管及禁止进口产品
此项目有
Zeolite-supported iron catalysts for allyl alcohol synthesis from glycerol.
Sanchez G, et al.
Applied Catalysis A: General, 590, 130-142 (2016)
Synthesis of propylene from renewable allyl alcohol by photocatalytic transfer hydrogenolysis
Caner J, et al.
Catalysis Science & Technology, 4(11), 4093-4098 (2014)
Gregory M Mullen et al.
Journal of the American Chemical Society, 136(17), 6489-6498 (2014-04-08)
Partial oxidation of alcohols is a topic of great interest in the field of gold catalysis. In this work, we provide evidence that the partial oxidation of allyl alcohol to its corresponding aldehyde, acrolein, over oxygen-precovered gold surfaces occurs via
Hydrosilylation of allyl alcohol with [HSiMe2OSiO1.5]8: octa (3-hydroxypropyldimethylsiloxy) octasilsesquioxane and its octamethacrylate derivative as potential precursors to hybrid nanocomposites.
Zhang C and Laine RM.
Journal of the American Chemical Society, 122(29), 6979-6988 (2000)
Deoxydehydration of glycerol to allyl alcohol catalyzed by rhenium derivatives.
Canale V, et al.
Catalysis Science & Technology, 4(10), 3697-3704 (2014)
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