240532
烯丙醇
≥99%, liquid
别名:
2-丙烯-1-醇
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关于此项目
线性分子式:
CH2=CHCH2OH
化学文摘社编号:
分子量:
58.08
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
203-470-7
MDL number:
Beilstein/REAXYS Number:
605307
Assay:
≥99%
Form:
liquid
产品名称
烯丙醇, ≥99%
vapor density
2 (vs air)
Quality Level
vapor pressure
23.8 mmHg ( 25 °C)
assay
≥99%
form
liquid
autoignition temp.
712 °F
expl. lim.
18 %
refractive index
n20/D 1.412 (lit.)
bp
96-98 °C (lit.)
mp
−129 °C (lit.)
solubility
alcohol: miscible(lit.), chloroform: miscible(lit.), diethyl ether: miscible(lit.), water: miscible(lit.)
density
0.854 g/mL at 25 °C (lit.)
functional group
hydroxyl
SMILES string
OCC=C
InChI
1S/C3H6O/c1-2-3-4/h2,4H,1,3H2
InChI key
XXROGKLTLUQVRX-UHFFFAOYSA-N
General description
烯丙醇是工业上重要的烯醇。它是合成各种烯丙基衍生物的原料，如烯丙基二甘醇二碳酸酯、烯丙基缩水甘油醚、1,4-丁二醇和聚(苯乙烯-烯丙醇)等。这些衍生物可用于镜片、偶联剂、增塑剂、交联剂和涂料添加剂中。烯丙醇可以通过铼催化的甘油脱氧脱水反应进行制备。
烯丙醇在预吸附氧的金表面上的部分氧化已被研究。
Application
使用Pd/TiO2 催化烯丙醇发生光催化转移氢解反应，可制备丙烯。
烯丙醇被用于酵母菌（Saccharomyces cerevisiae）培养中。
用于诱导肝脏损坏的小鼠模型，该模型用于研究肝细胞毒性和肝干细胞介导修复的机制。
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signalword
Danger
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
71.6 °F - closed cup
flash_point_c
22 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Classifications
Acute Tox. 2 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 3 - Eye Irrit. 2 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT SE 3
法规信息
监管及禁止进口产品
此项目有
Synthesis of propylene from renewable allyl alcohol by photocatalytic transfer hydrogenolysis
Caner J, et al.
Catalysis Science & Technology, 4(11), 4093-4098 (2014)
Zeolite-supported iron catalysts for allyl alcohol synthesis from glycerol.
Sanchez G, et al.
Applied Catalysis A: General, 590, 130-142 (2016)
Orla M Wilson et al.
Journal of the American Chemical Society, 128(14), 4510-4511 (2006-04-06)
We report a particle size dependence for the rate of hydrogenation of allyl alcohol using 1.3-1.9 nm Pd dendrimer-encapsulated nanoparticle (DEN) catalysts. For particles with diameters of <1.5 nm and containing <147 Pd atoms, the modulation in catalytic activity is
全球贸易项目编号
| 货号 | GTIN |
|---|---|
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| 240532-100ML | 04061823361019 |
| 240532-500ML | 04061823361026 |
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