240761
1-己烯
≥99%
别名:
1-n-Hexene
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关于此项目
线性分子式:
CH3(CH2)3CH=CH2
化学文摘社编号:
分子量:
84.16
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
209-753-1
Beilstein/REAXYS Number:
1209240
MDL number:
产品名称
1-己烯, ≥99%
InChI key
LIKMAJRDDDTEIG-UHFFFAOYSA-N
InChI
1S/C6H12/c1-3-5-6-4-2/h3H,1,4-6H2,2H3
SMILES string
CCCCC=C
vapor density
3 (vs air)
vapor pressure
155 mmHg ( 21.1 °C)
assay
≥99%
form
liquid
autoignition temp.
487 °F
refractive index
n20/D 1.388 (lit.)
bp
60-66 °C (lit.)
density
0.678 g/mL at 25 °C (lit.)
functional group
allyl
Quality Level
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Application
- 1-己烯在高分子量聚合物中的合成：使用Lewis酸催化剂从1-己烯和丙烯酸甲酯合成高分子量共聚物，展示了材料科学领域的先进应用，特别是在开发耐用和多功能高分子材料方面（Wan et al., 2024）。
- 1-己烯在质子交换膜增强中的作用：利用1-己烯表征和增强功能多孔质子交换膜的物理化学性质，突出了它在提高燃料电池技术的能源效率和性能方面的关键作用（Ponomar et al., 2024）。
General description
1-己烯的聚合动力学已通过使用五锆胺双酚酸盐催化剂家族进行研究。由一系列铪配合物催化的1-己烯的聚合反应已有研究。
signalword
Danger
hcodes
Hazard Classifications
Asp. Tox. 1 - Flam. Liq. 2
supp_hazards
存储类别
3 - Flammable liquids
wgk
WGK 2
flash_point_f
-13.0 °F - closed cup
flash_point_c
-25.0 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Takahiro Yasumoto et al.
Dalton transactions (Cambridge, England : 2003), 42(25), 9120-9128 (2012-12-14)
Non-bridged half-metallocene dimethyl complexes of group 4 metals 2a-4a with an N-4-methoxyphenyl(iminomethyl)pyrrolyl ligand 1a were synthesized and characterized by NMR spectroscopy and X-ray analysis. Upon activation with [Ph3C][B(C6F5)4], these complexes became active catalysts for the polymerization of 1-hexene. A series
D Keith Steelman et al.
Journal of the American Chemical Society, 135(16), 6280-6288 (2013-03-23)
The kinetics of 1-hexene polymerization using a family of five zirconium amine bis-phenolate catalysts, Zr[tBu-ON(X)O]Bn2 (where X = THF (1), pyridine (2), NMe2 (3), furan (4), and SMe (5)), has been investigated to uncover the mechanistic effect of varying the
Lingyan Gong et al.
Journal of colloid and interface science, 569, 219-228 (2020-03-01)
The current mechanism of surfactant enhanced oil recovery (EOR) mainly relies on forming middle-phase microemulsions to get ultra-low oil-water interfacial tension. However, residual oil can also be recovered using low concentration surfactant solutions without microemulsion formation, and the interaction between
Yuichi Ito et al.
Implant dentistry, 24(4), 477-479 (2015-06-04)
The evaluation of bone quality at the site of the alveolar bone for a dental implant is very important. This study presents an easy technique for direct evaluation of alveolar bone quality using nondecalcified cryofilm frozen sections on human alveolar
Chia-Hsiu Chen et al.
Journal of the American Chemical Society, 137(21), 6965-6971 (2015-05-12)
The stereochemistry, kinetics, and mechanism of olefin polymerization catalyzed by a set of zirconium-based metallocenes was studied by NMR using dissolution dynamic nuclear polarization (DNP). Hyperpolarized 1-hexene was polymerized in situ with a C2 symmetric catalyst, [(EBI)ZrMe][B(C6F5)4] (EBI = rac-(C2H4(1-indenyl)2))
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