产品名称
三甲氧基磷, ≥99%
vapor density
4.3 (vs air)
Quality Level
vapor pressure
17 mmHg ( 20 °C)
assay
≥99%
form
liquid
reaction suitability
reagent type: ligand
reaction type: Heck Reaction, reagent type: ligand
reaction type: Suzuki-Miyaura Coupling
refractive index
n20/D 1.408 (lit.)
bp
111-112 °C (lit.)
mp
−78 °C (lit.)
density
1.052 g/mL at 25 °C (lit.)
SMILES string
COP(OC)OC
InChI
1S/C3H9O3P/c1-4-7(5-2)6-3/h1-3H3
InChI key
CYTQBVOFDCPGCX-UHFFFAOYSA-N
General description
Trimethyl phosphite is an organophosphorus compound commonly used as a polymerization catalyst, coating additive, and as an intermediate in the synthesis of flame retardants. In addition, it is also used as an activating reagent in amide formation.
Application
Trimethyl phosphite can be used as a ligand in the synthesis of allyliridium phosphite complexes by direct reaction with allyliridium 1,5-cyclooctadiene complex.
Still not finding the right product?
Explore all of our products under 三甲氧基磷
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
supp_hazards
存储类别
3 - Flammable liquids
wgk
WGK 1
flash_point_f
82.4 °F - closed cup
flash_point_c
28 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
监管及禁止进口产品
此项目有
相关内容
Phosphine Ligand Application Guide
An efficient protocol for the amidation of carboxylic acids promoted by trimethyl phosphite and iodine
Luo QL, et al.
European Journal of Organic Chemistry (2011)
Allyliridium phosphite complexes. Synthesis and chemistry
Muetterties EL, et al.
Organometallics, 1(12), 1562-1567 (1982)
Shinichi Yamabe et al.
The journal of physical chemistry. A, 114(43), 11699-11707 (2010-10-15)
Density functional theory calculations of the title reaction, P(OCH₃)₃ + (H₂O)(n) in CH₃CN, were conducted, where n is the number of water molecules. Two routes, the routes suggested by (A) Aksnes and (B) Arbuzov, were traced with various n values.
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 240907-25G | 04061824077971 |
| 240907-100G | 04061824077964 |