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Merck
CN

241636

联二噻吩

99%

别名:

2,2′-二噻吩, 2,2′-联噻吩

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关于此项目

经验公式(希尔记法):
C8H6S2
化学文摘社编号:
分子量:
166.26
UNSPSC Code:
12352103
NACRES:
NA.23
PubChem Substance ID:
EC Number:
207-767-2
Beilstein/REAXYS Number:
3039
MDL number:
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产品名称

联二噻吩, 99%

InChI key

OHZAHWOAMVVGEL-UHFFFAOYSA-N

InChI

1S/C8H6S2/c1-3-7(9-5-1)8-4-2-6-10-8/h1-6H

SMILES string

c1csc(c1)-c2cccs2

assay

99%

bp

260 °C (lit.)

mp

32-33 °C (lit.)

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Application

2,2′-联噻吩可通过聚合形成聚(2,2′-联噻吩),电沉积在氧化铟锡(ITO)底物上,用于制造电致变色器件。它还可用于形成电极材料,用于开发超级电容器。
可在铑催化的杂环芳烃和芳基碘的C-H芳基化反应中用作底物。

General description

2,2′-联噻吩是一种电子传输材料,其π电子存在于系统中,有助于电荷迁移。

存储类别

10 - Combustible liquids

wgk

WGK 3

flash_point_f

230.0 °F - closed cup

flash_point_c

110 °C - closed cup

ppe

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)


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Weiying He et al.
Nature communications, 9(1), 3866-3866 (2018-09-27)
Nickel-catalyzed catalyst transfer polycondensation (CTP) of thiophenes is an efficient strategy for the controlled synthesis of polythiophenes. However, a detailed view of its reaction mechanism has remained elusive with unresolved questions regarding the geometry and bonding of critical Ni(0) thiophene intermediates.
5, 5 `-Bis (dimesitylboryl)-2, 2 `-bithiophene and 5, 5 ``-bis (dimesitylboryl)-2, 2 `: 5 `, 2 ``-terthiophene as a novel family of electron-transporting amorphous molecular materials.
Noda T and Shirota Y
Journal of the American Chemical Society, 120(37), 9714-9715 (1998)
Applications of Poly (indole-6-carboxylic acid-co-2, 2?-bithiophene) Films in High-Contrast Electrochromic Devices.
Kuo C, et al.
Coatings, 8(3), 102-102 (2018)
Electrode material dependent p-or n-like thermoelectric behavior of single electrochemically synthesized poly (2, 2?-bithiophene) layer?application to thin film thermoelectric generator.
Kublitski J, et al.
Journal of Solid State Electrochemistry, 20(8), 2191-2196 (2016)
Shuichi Yanagisawa et al.
Journal of the American Chemical Society, 128(36), 11748-11749 (2006-09-07)
A new method for the catalytic C-H arylation of heteroarenes and arenes that manifests high activity paired with reasonably broad scope was developed. Under the catalytic influence of RhCl(CO){P[OCH(CF3)2]3}2 and Ag2CO3, the direct C-H arylation of heteroarenes/arenes with aryl/heteroaryl iodides

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