241725
三异丙氯硅烷
97%
别名:
三异丙基氯硅烷, TIPSCl, 三异丙基氯甲硅烷, 三异丙氯硅烷
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关于此项目
线性分子式:
[(CH3)2CH]3SiCl
化学文摘社编号:
分子量:
192.80
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
1737446
Assay:
97%
Form:
liquid
vapor pressure
1.16 mmHg ( 20 °C)
Quality Level
assay
97%
form
liquid
refractive index
n20/D 1.452 (lit.)
bp
198 °C/739 mmHg (lit.)
density
0.901 g/mL at 25 °C (lit.)
SMILES string
CC(C)[Si](Cl)(C(C)C)C(C)C
InChI
1S/C9H21ClSi/c1-7(2)11(10,8(3)4)9(5)6/h7-9H,1-6H3
InChI key
KQIADDMXRMTWHZ-UHFFFAOYSA-N
Application
TIPS 取代炔烃可用于由铬卡宾络合物制备硅基乙烯基烯酮。
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
147.2 °F - closed cup
flash_point_c
64 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Greene, T.W. Wuts, P.G.M.
Protective Groups in Organic Synthesis (1991)
William H Moser et al.
The Journal of organic chemistry, 71(17), 6542-6546 (2006-08-12)
Stable silyl vinylketenes were prepared via the thermal reaction of Fischer carbene complexes with triisopropylsilyl- or tert-butyldimethylsilyl-substituted alkynes. The ability of these silyl vinylketenes to participate with carbenoid reagents in [4 + 1] annulation reactions was investigated. The best results
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 241725-10G | 04061825410807 |
| 241725-250G | 04061833398067 |
| 241725-50G | 04061825411019 |