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经验公式(希尔记法):
C6H12O3
化学文摘社编号:
分子量:
132.16
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
80117
产品名称
(R)-(-)-甘油醇缩丙酮, 98%
Quality Level
InChI
1S/C6H12O3/c1-6(2)8-4-5(3-7)9-6/h5,7H,3-4H2,1-2H3/t5-/m1/s1
SMILES string
CC1(C)OC[C@@H](CO)O1
InChI key
RNVYQYLELCKWAN-RXMQYKEDSA-N
assay
98%
form
liquid
optical activity
[α]20/D −13.7°, neat
optical purity
ee: 98% (GLC)
refractive index
n20/D 1.434 (lit.)
bp
72-73 °C/8 mmHg (lit.)
density
1.062 g/mL at 25 °C (lit.)
functional group
ether
hydroxyl
ketal
storage temp.
2-8°C
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Application
(R)-(-)-2,2-二甲基-1,3-二氧戊环-4-甲醇可用于制备:
- ( R )-2,2-二甲基-4-苯氧基甲基-1,3-二氧杂环戊烷
- (( S )-(2,2-二甲基-1,3-二氧杂环戊烷-4-基)甲基 4-甲基苯磺酸酯)-1,3-二氧杂环戊烷
- ( S )-甘油醛缩丙酮
- 四氧杂螺十一烷、甘油二酯、磷酸甘油酯和螺吡喃。
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
174.2 °F - closed cup
flash_point_c
79 °C - closed cup
ppe
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
法规信息
新产品
此项目有
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Ji N, et al.
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Xiang G and McLaughlin LW.
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Bernard T Golding, et al.
Tetrahedron Letters, 34, 6459-6462 (1993)
René Pemha et al.
Marine drugs, 18(2) (2020-02-23)
A series of novel substituted 1-O-alkylglycerols (AKGs) containing methoxy (8), gem-difluoro (9), azide (10) and hydroxy (11) group at 12 position in the alkyl chain were synthesized from commercially available ricinoleic acid (12). The structures of these new synthesized AKGs
2- and 8- functionalized 1,4,7,10-tetraoxaspiro[5.5]undecanes.: II. Synthesis of (+)-E,E and (?)-Z,E structures from chiral isopropylideneglycerols.
Marielle Lemaire
Tetrahedron Asymmetry, 4. 9, 2101-2108 (1993)
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