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242926

富马酸二甲酯

Name: 富马酸二甲酯
Brand: ALDRICH

97%

别名:

(2E)-2-丁烯二酸二甲酯, (E)-2-丁烯二酸二甲酯, 反式-1,2-亚乙二酸二甲酯, 反式-亚乙二酸二甲酯, 反式丁烯二酸二甲酯, 富马酸甲酯, 异戊酸二甲酯

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关于此项目

线性分子式:

CH₃OCOCH=CHCOOCH₃

化学文摘社编号:

624-49-7

分子量:

144.13

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24854591

EC Number:

210-849-0

Beilstein/REAXYS Number:

774590

MDL number:

MFCD00064438

Assay:

97%

Form:

solid

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属性

Quality Level

200

assay

97%

form

solid

bp

192-193 °C (lit.)

mp

102-106 °C (lit.)

functional group

ester

SMILES string

[H]\C(=C(\[H])C(=O)OC)C(=O)OC

InChI

1S/C6H8O4/c1-9-5(7)3-4-6(8)10-2/h3-4H,1-2H3/b4-3+

InChI key

LDCRTTXIJACKKU-ONEGZZNKSA-N

Gene Information

human ... KEAP1(9817)

说明

Application

富马酸二甲酯可用于：

制备一种加合物[二甲基-(+)-(11R,12R)-9,10-二氢-9,10-乙撑蒽-11,12-二羧酸]。
作为配体合成Ni(II)基催化体系，用于N-磺酰基氮丙啶和有机锌试剂的Negishi烷基化反应。
作为配体合成零价钌金属配合物，Ru(η⁶-1,3,5-环辛三烯)(η²-富马酸二甲酯)₂。

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pictograms

GHS07,GHS09

signalword

Warning

hcodes

H312,H315,H317,H335,H411

pcodes

P261 - P264 - P271 - P273 - P280 - P302 + P352 + P312

Hazard Classifications

Acute Tox. 4 Dermal - Aquatic Chronic 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Ru (η6-1, 3, 5-cyclooctatriene)(η2-dimethyl fumarate) 2: a novel, versatile zerovalent ruthenium complex with electron-deficient olefinic ligands

Mitsudo T, et al.

Journal of Organometallic Chemistry, 689, 4530-4539 (2004)

Importance of c*--h based modes and large amplitude motion effects in vibrational circular dichroism spectra: the case of the chiral adduct of dimethyl fumarate and anthracene

Passarello M, et al.

The Journal of Physical Chemistry A, 118, 4339-4350 (2014)

Importance of C*-H based modes and large amplitude motion effects in vibrational circular dichroism spectra: the case of the chiral adduct of dimethyl fumarate and anthracene.

Marco Passarello et al.

The journal of physical chemistry. A, 118(24), 4339-4350 (2014-05-21)

The role played by the C*-H based modes (C* being the chiral carbon atom) and the large amplitude motions in the vibrational absorption (VA) and vibrational circular dichroism (VCD) spectra is investigated. The example of an adduct of dimethyl fumarate

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全球贸易项目编号

货号	GTIN
1479031-20MG	04061833852903
242926-100G	04061831819243
242926-25G	04061825590714