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Merck
CN

243590

高铼酸钾

99%

别名:

Potassium oxido(trioxo)rhenium, Potassium tetraoxorhenate(1-)

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关于此项目

线性分子式:
KReO4
化学文摘社编号:
分子量:
289.30
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
233-953-8
MDL number:
Assay:
99%
Form:
powder
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Quality Level

assay

99%

form

powder

reaction suitability

core: potassium

refractive index

n20/D 1.643 (lit.)

mp

550 °C (lit.)

density

4.887 g/mL at 25 °C (lit.)

SMILES string

[K+].[O-][Re](=O)(=O)=O

InChI

1S/K.4O.Re/q+1;;;;-1;

InChI key

QFKRWIFGDGKWLM-UHFFFAOYSA-N

Application

在环戊二烯基三羰基铼络合物的制备中 KReO4 的还原有望成为合成锝和铼有机金属放射性药物的模型。


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存储类别

5.1B - Oxidizing hazardous materials

wgk

WGK 3

ppe

dust mask type N95 (US), Eyeshields, Gloves, type P3 (EN 143) respirator cartridges



历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Spradau, T.W. Katzenellenbogen, J.A.
Organometallics, 17, 2009-2009 (1998)
Yuee Feng et al.
Inorganic chemistry, 48(23), 11058-11066 (2009-11-06)
The detailed syntheses of complexes of the form [Re(O)(X)(RNCH(2)CH(2))(2)N(Me)] (X = Me, Cl, I, R = mesityl, C(6)F(5)), 1-3, incorporating diamidoamine ancillary ligands are described. X-ray crystal structures for the complexes [Re(O)(Me)((C(6)F(5))NCH(2)CH(2))(2)N(Me)], 1a, [Re(O)(I)((C(6)F(5))N CH(2)CH(2))(2)N(Me)], 3a, and [Re(O)(I)((Mes)NCH(2))(2)N(Me)], 3b, are
Mark J Bailey et al.
Advanced healthcare materials, 1(4), 437-442 (2012-11-28)
Configuring RE(2) O(3) nanocrystals with pseudo-2D morphologies confers substantive gains in relaxivities over equivalent spherical counterparts. The most promising arises from Gd(2) O(3) whose ionic transverse and longitudinal relaxivities were as high as r(1) = 12.7 mM(-1) s(-1) and r(2)



全球贸易项目编号

货号GTIN
243590-5G04061832968537
243590-25G04061838138552