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Merck
CN

244775

Sigma-Aldrich

三苯基氢化锡

别名:

三苯基氢化锡, 三苯基锡烷

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线性分子式:
(C6H5)3SnH
化学文摘社编号:
分子量:
351.03
EC 号:
MDL编号:
UNSPSC代码:
12352002
PubChem化学物质编号:
NACRES:
NA.22
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表单

solid

反应适用性

reagent type: reductant

折射率

n20/D 1.632 (lit.)

沸点

163-165 °C/0.3 mmHg (lit.)

mp

28 °C (lit.)

密度

1.374 g/mL at 25 °C (lit.)

储存温度

2-8°C

SMILES字符串

c1ccc(cc1)[SnH](c2ccccc2)c3ccccc3

InChI

1S/3C6H5.Sn.H/c3*1-2-4-6-5-3-1;;/h3*1-5H;;

InChI key

NFHRNKANAAGQOH-UHFFFAOYSA-N

应用

氢化三苯基锡可作为还原剂用于:
  • 在催化量的AIBN存在下的还原性去硒烯化反应。。
  • 烯烃的自由基氢锡化。
  • α,β-不饱和酮和酯的还原。

它也可以在9-硼二环[3.3.1]壬烷(9-BBN)作为引发剂的存在下用作自由基还原反应中的自由基前体。

象形图

Skull and crossbonesEnvironment

警示用语:

Danger

危险分类

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1

储存分类代码

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

闪点(°F)

235.4 °F - closed cup

闪点(°C)

113 °C - closed cup

个人防护装备

dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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