244775
三苯基氢化锡
别名:
三苯基氢化锡, 三苯基锡烷
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关于此项目
线性分子式:
(C6H5)3SnH
化学文摘社编号:
分子量:
351.03
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352002
EC Number:
212-967-8
MDL number:
Form:
solid
InChI key
NFHRNKANAAGQOH-UHFFFAOYSA-N
InChI
1S/3C6H5.Sn.H/c3*1-2-4-6-5-3-1;;/h3*1-5H;;
SMILES string
c1ccc(cc1)[SnH](c2ccccc2)c3ccccc3
form
solid
reaction suitability
reagent type: reductant
refractive index
n20/D 1.632 (lit.)
bp
163-165 °C/0.3 mmHg (lit.)
mp
28 °C (lit.)
density
1.374 g/mL at 25 °C (lit.)
storage temp.
2-8°C
Application
氢化三苯基锡可作为还原剂用于：
它也可以在9-硼二环[3.3.1]壬烷（9-BBN）作为引发剂的存在下用作自由基还原反应中的自由基前体。
- 在催化量的AIBN存在下的还原性去硒烯化反应。。
- 烯烃的自由基氢锡化。
- α，β-不饱和酮和酯的还原。
它也可以在9-硼二环[3.3.1]壬烷（9-BBN）作为引发剂的存在下用作自由基还原反应中的自由基前体。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
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