form
solid
reaction suitability
reagent type: reductant
refractive index
n20/D 1.632 (lit.)
bp
163-165 °C/0.3 mmHg (lit.)
mp
28 °C (lit.)
density
1.374 g/mL at 25 °C (lit.)
storage temp.
2-8°C
SMILES string
c1ccc(cc1)[SnH](c2ccccc2)c3ccccc3
InChI
1S/3C6H5.Sn.H/c3*1-2-4-6-5-3-1;;/h3*1-5H;;
InChI key
NFHRNKANAAGQOH-UHFFFAOYSA-N
Application
氢化三苯基锡可作为还原剂用于：
它也可以在9-硼二环[3.3.1]壬烷（9-BBN）作为引发剂的存在下用作自由基还原反应中的自由基前体。
- 在催化量的AIBN存在下的还原性去硒烯化反应。。
- 烯烃的自由基氢锡化。
- α，β-不饱和酮和酯的还原。
它也可以在9-硼二环[3.3.1]壬烷（9-BBN）作为引发剂的存在下用作自由基还原反应中的自由基前体。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Ítalo Braga Castro et al.
Environmental toxicology and chemistry, 31(5), 947-954 (2012-03-14)
The imposex incidence was appraised in South American gastropods, considering the scenario before and after the global ban of tributyltin (TBT). A statistically significant reduction in imposex indexes was observed in Stramonita haemastoma collected in 2006 and 2010 from areas
Sartaj Tabassum et al.
Metallomics : integrated biometal science, 4(2), 205-217 (2011-12-21)
The novel organotin complex 1-{(2-hydroxyethyl)amino}-2-amino-1,2-dideoxy-D-glucose triphenyltin(iv) (GATPT) was synthesized by the reaction of N-glycoside ligand and triphenyltin(iv) chloride. GATPT was characterized by elemental analyses, polarimetry, IR, CD, UV and multinuclear ((1)H, (13)C, (119)Sn) 1D and 2D NMR. The interaction of
Free radical hydrostannylation of unactivated alkenes with chiral trialkylstannanes
Kavanagh Y, et al.
Organometallics, 30(16), 4387-4392 (2011)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 244775-25G | 04061838347886 |
| 244775-5G | 04061825770062 |