244775
三苯基氢化锡
别名:
三苯基氢化锡, 三苯基锡烷
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关于此项目
线性分子式:
(C6H5)3SnH
化学文摘社编号:
分子量:
351.03
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352002
EC Number:
212-967-8
MDL number:
Form:
solid
InChI key
NFHRNKANAAGQOH-UHFFFAOYSA-N
InChI
1S/3C6H5.Sn.H/c3*1-2-4-6-5-3-1;;/h3*1-5H;;
SMILES string
c1ccc(cc1)[SnH](c2ccccc2)c3ccccc3
form
solid
reaction suitability
reagent type: reductant
refractive index
n20/D 1.632 (lit.)
bp
163-165 °C/0.3 mmHg (lit.)
mp
28 °C (lit.)
density
1.374 g/mL at 25 °C (lit.)
storage temp.
2-8°C
Application
氢化三苯基锡可作为还原剂用于：
它也可以在9-硼二环[3.3.1]壬烷（9-BBN）作为引发剂的存在下用作自由基还原反应中的自由基前体。
- 在催化量的AIBN存在下的还原性去硒烯化反应。。
- 烯烃的自由基氢锡化。
- α，β-不饱和酮和酯的还原。
它也可以在9-硼二环[3.3.1]壬烷（9-BBN）作为引发剂的存在下用作自由基还原反应中的自由基前体。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Lin Yu et al.
Journal of hazardous materials, 192(3), 1860-1868 (2011-08-09)
Triphenyltin (TPT) has high binding affinity with the retinoid X receptor (RXR) in animals. The natural ligand of RXR, 9-cis-retinoic acid (RA), is known to induce featured malformations in vertebrate embryos by disrupting RA signal. Limited information is available on
Triethylborane induced selective 1, 4-reduction of α, β-unsaturated carbonyl compounds with triphenyltin hydride or tributyltin hydride
Nozaki K, et al.
Bulletin of the Chemical Society of Japan, 64(8), 2585-2587 (1991)
On the use of 9-borabicyclo [3.3. 1] nonane as an initiator for low-temperature free-radical reductions
Perchyonok VT and Schiesser CH
Tetrahedron Letters, 39(30), 5437-5438 (1998)
Free radical hydrostannylation of unactivated alkenes with chiral trialkylstannanes
Kavanagh Y, et al.
Organometallics, 30(16), 4387-4392 (2011)
Fabiane G Antes et al.
Environmental science & technology, 45(24), 10524-10530 (2011-11-15)
Triphenyltin (TPhT) is a biocide used worldwide in agriculture, especially in rice crop farming. The distribution and dissipation of TPhT in rice fields, as well as uptake of TPhT and other phenyltin compounds (monophenyltin, MPhT, and diphenyltin, DPhT) is still
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