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246050

1,5-环辛二烯

Name: 1,5-环辛二烯
Brand: ALDRICH

purified by redistillation, ≥99%

别名:

1,5-COD, cis-1,5-Cyclooctadiene, COD

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关于此项目

经验公式（希尔记法）:

C₈H₁₂

化学文摘社编号:

111-78-4

分子量:

108.18

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24854773

EC Number:

203-907-1

Beilstein/REAXYS Number:

2036542

MDL number:

MFCD00001752

Assay:

≥99%

Form:

liquid

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属性

Quality Level

100

vapor pressure

25.8 mmHg ( 37.7 °C), 6.8 mmHg ( 25 °C)

assay

≥99%

form

liquid

autoignition temp.

431 °F

purified by

redistillation

does not contain

stabilizer

refractive index

n20/D 1.493 (lit.)

bp

149-150 °C (lit.)

mp

−69 °C (lit.)

density

0.882 g/mL at 25 °C (lit.)

SMILES string

C1CC=CCCC=C1

InChI

1S/C8H12/c1-2-4-6-8-7-5-3-1/h1-2,7-8H,3-6H2/b2-1-,8-7-

InChI key

VYXHVRARDIDEHS-QGTKBVGQSA-N

说明

Application

1，5-环辛二烯被用作合成氨基茚衍生物的催化剂，通过酮亚胺与内部和末端炔烃的环合反应。

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pictograms

GHS02,GHS08,GHS07,GHS09

signalword

Danger

hcodes

H226,H302 + H332,H304,H410

pcodes

P210 - P233 - P273 - P301 + P310 - P304 + P340 + P312 - P331

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Flam. Liq. 3

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

100.4 °F - closed cup

flash_point_c

38 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Catalytic [3 + 2] annulation of ketimines with alkynes via C-H activation by a cationic iridium(cod) complex.

Midori Nagamoto et al.

Chemical communications (Cambridge, England), 50(47), 6274-6277 (2014-05-07)

[3 + 2] Annulation of ketimines with internal and terminal alkynes proceeded via C-H activation to give aminoindene derivatives in high yields, which is catalyzed by a cationic iridium complex coordinated with 1,5-cyclooctadiene (cod).

Effects of Magnetic Field Cycle on the Polarization Transfer from Parahydrogen to Heteronuclei through Long-Range J-Couplings.

Eleonora Cavallari et al.

The journal of physical chemistry. B, 119(31), 10035-10041 (2015-07-15)

Hyperpolarization of (13)C carboxylate signals of metabolically relevant molecules, such as acetate and pyruvate, was recently obtained by means of ParaHydrogen Induced Polarization by Side Arm Hydrogenation (PHIP-SAH). This method relies on functionalization of the carboxylic acid with an unsaturated

Synthesis of tetra-substituted imidazoles and 2-imidazolines by Ni(0)-catalyzed dehydrogenation of benzylic-type imines.

Adrian Tlahuext-Aca et al.

Dalton transactions (Cambridge, England : 2003), 43(42), 15997-16005 (2014-09-19)

Ni(0)-catalyzed dehydrogenation of benzylic-type imines was performed to yield asymmetrical tetra-substituted imidazoles and 2-imidazolines. This was achieved with a single operational step while maintaining good selectivity and atom economy. The catalytic system shows low to moderate tolerance for fluoro-, trifluoromethyl-

全球贸易项目编号

货号	GTIN
246050-800ML	04061837331572
246050-100ML	04061825849997