Merck
CN

246352

Sigma-Aldrich

氨基甲酸甲酯

98%

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别名:
尿基烷
线性分子式:
NH2COOCH3
CAS号:
分子量:
75.07
EC 号:
MDL编号:
PubChem化学物质编号:
NACRES:
NA.22

质量水平

检测方案

98%

形式

crystals

bp

176-177 °C (lit.)

mp

56-58 °C (lit.)

溶解性

alcohol: freely soluble(lit.)
water: freely soluble(lit.)

SMILES字符串

COC(N)=O

InChI

1S/C2H5NO2/c1-5-2(3)4/h1H3,(H2,3,4)

InChI key

GTCAXTIRRLKXRU-UHFFFAOYSA-N

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应用

氨基甲酸甲酯被用于合成受保护的氨基环丙烷

象形图

Exclamation markHealth hazard

警示用语:

Warning

危险声明

危险分类

Carc. 2 - Eye Irrit. 2

储存分类代码

11 - Combustible Solids

WGK

WGK 3

个人防护装备

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


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Shingo Ishikawa et al.
Angewandte Chemie (International ed. in English), 52(38), 10060-10063 (2013-08-06)
Easy as 1,2,3: Reaction of methyl carbamate, triethyl orthoformate, and readily available alkenes provides a highly practical preparation of protected aminocyclopropanes. The reaction proceeds with preferential cis addition to alkenes, and cleavage of the methyl carbamate gives the free aminocyclopropanes
Joshua A Hartsel et al.
Bioorganic & medicinal chemistry letters, 22(14), 4593-4598 (2012-06-29)
To identify potential human-safe insecticides against the malaria mosquito we undertook an investigation of the structure-activity relationship of aryl methylcarbamates inhibitors of acetylcholinesterase (AChE). Compounds bearing a β-branched 2-alkoxy or 2-thioalkyl group were found to possess good selectivity for inhibition
Geert Van Biesen et al.
Electrophoresis, 27(22), 4456-4468 (2006-10-24)
Ammonium perfluorooctanoate (APFOA) was investigated as an MS-friendly surfactant for the analysis of a mixture of ten N-methylcarbamates with MEKC-ESI-MS. Because of the relatively low boiling point of perfluorooctanoic acid ( approximately 190 degrees C), APFOA can be introduced into
D F K Rawn et al.
Food additives and contaminants, 21(6), 555-563 (2004-06-19)
Infants and young children consume fruit juices and drinks at rates exceeding those of older children and adults. Carbamate pesticides are known to be used on a broad spectrum of crops, including orchard and vine crops such as apples and
Xiangyun Lin et al.
Journal of separation science, 34(2), 202-209 (2011-01-20)
This paper described a simple, rapid and efficient method for the determination of N-methyl carbamate pesticides in tomato, cucumber, carrot and lettuce samples by dispersive liquid-liquid microextraction coupled with HPLC-diode array detection. Some experimental parameters that influenced the extraction efficiency

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